La-doped SrTiO3 interconnect materials for anode-supported flat-tubular solid oxide fuel cells

被引:40
作者
Park, Beom-Kyeong [1 ,2 ]
Lee, Jong-Won [1 ]
Lee, Seung-Bok [1 ]
Lim, Tak-Hyoung [1 ]
Park, Seok-Joo [1 ]
Song, Rak-Hyun [1 ]
Im, Won Bin [3 ]
Shin, Dong-Ryul [1 ]
机构
[1] Korea Inst Energy Res, Fuel Cell Res Ctr, Taejon 305343, South Korea
[2] Univ Sci & Technol, Dept Adv Energy Technol, Taejon 305350, South Korea
[3] Chonnam Natl Univ, Sch Mat Sci & Engn, Kwangju 500757, South Korea
关键词
Anode-supported solid oxide fuel cell; Flat-tubular cell; Interconnect; Strontium titanate; Sr deficiency; STRONTIUM-TITANATE; METALLIC INTERCONNECTS; THERMAL-EXPANSION; DEFECT STRUCTURE; LANTHANUM; CONDUCTIVITY; PEROVSKITE; BEHAVIOR; FABRICATION; STABILITY;
D O I
10.1016/j.ijhydene.2011.10.125
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An interconnect layer in an anode-supported flat-tubular solid oxide fuel cell connects electrically unit cells and separates fuel from oxidant in the adjoining cells. Nano-sized La-doped SrTiO3 for the interconnect is synthesized in this study by the Pechini method using citric acid. The materials with stoichiometric and Sr-deficient compositions are prepared and sintered in an oxidizing atmosphere. The synthesized fine powders exhibit high sinterability, leading to near-full densification. The Sr deficiency plays a crucial role in mechanical, electrical and thermal expansion properties. The interconnect is coated using the synthesized powder on a porous flat-tubular anode support by a screen printing process. The thin and dense layer is obtained after co-sintering in air, and the interconnect/anode interface remains intact upon reduction. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:4319 / 4327
页数:9
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