Evolution of magnetostructural transition and magnetocaloric effect with Al doping in MnCoGe1-xAlx compounds

被引:74
作者
Bao, L. F. [1 ,2 ]
Hu, F. X. [1 ,2 ]
Wu, R. R. [1 ,2 ]
Wang, J. [1 ,2 ]
Chen, L. [1 ,2 ]
Sun, J. R. [1 ,2 ]
Shen, B. G. [1 ,2 ]
Li, L. [3 ]
Zhang, B. [3 ]
Zhang, X. X. [3 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, State Key Lab Magnetism, Inst Phys, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, State Key Lab Magnetism, Inst Phys, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
magnetocaloric effect; magnetostructural transition; MnCoGe1-xAlx compounds; MARTENSITIC-TRANSFORMATION; METAMAGNETIC TRANSITION; MAGNETIC-PROPERTIES; TEMPERATURE;
D O I
10.1088/0022-3727/47/5/055003
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effect of Al doping in MnCoGe1-xAlx compounds has been investigated. The substitution of Al for Ge enhances Mn-Mn covalent bonding by shortening the distance of nearest Mn atom layers, and thus stabilizes the hexagonal structure. As a result, first-order magnetostructural transition between ferromagnetic martensite and paramagnetic austenite takes place for the optimized compositions (x = 0.01, 0.02). Accompanied with the magnetostructural transition, large magnetocaloric effect (MCE) is observed. More doping of Al(x = 0.03, 0.04) leads to the separation of magnetic and structural transitions and remarkable reduction of MCE.
引用
收藏
页数:6
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