Slurry Impregnation of ZrO2 Extrudates: Controlled EggShell Distribution of MoO3, Hydrodesulfurization Activity, Promotion by Co

被引：9

作者：

Kaluza, Ludek ^{[1
]}

Zdrazil, Miroslav ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague 6, Czech Republic

来源：

CATALYSIS LETTERS | 2009年 / 127卷 / 3-4期

关键词：

MoO3/ZrO2; Eggshell Mo catalyst; CoMo/ZrO2; CoMo/TiO2; Slurry impregnation; Benzothiophene hydrodesulfurization; SUPPORTED CATALYSTS; HDS CATALYSTS; GAMMA-ALUMINA; ZIRCONIA; TITANIA; RAMAN; HYDROGENATION; EPOXIDATION; PROPYLENE; PROFILES;

D O I：

10.1007/s10562-008-9692-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalysts with eggshell/uniform Mo concentration profiles were prepared by a reaction of ZrO2 and ZrO(OH)(2) extrudates with an aqueous slurry of MoO3. The thickness of the shell was regulated by the amount of MoO3. CoCO3 was adsorbed onto MoO3/ZrO2 from its aqueous slurry. The ZrO2-supported catalysts were compared to their TiO2-supported and industrial reference Al2O3-supported counterparts in a model reaction of benzothiophene hydrodesulfurization.

引用

页码：368 / 376

页数：9

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