Formation and crystal structure of an unexpected inclusion complex of a metal-free phthalocyanine and oxalic acid

被引：28

作者：

Liu, W ^{[1
]}

Lee, CH ^{[1
]}

Li, HW ^{[1
]}

Lam, CK ^{[1
]}

Wang, JZ ^{[1
]}

Mak, TCW ^{[1
]}

Ng, DKP ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b111133g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of 3-(2,4-dimethyl-3-pentyloxy) phthalonitrile (2) with CeCl3 in the presence of 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU) in n-pentanol gives the corresponding metal-free phthalocyanine 3, which unexpectedly traps the oxalic acid in the crystal lattice forming a 1:1 inclusion complex.

引用

页码：628 / 629

页数：2

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