Novel 3D lanthanum oxalate metal-organic-framework: Synthetic, structural, luminescence and adsorption properties

被引：21

作者：

Calahorro, Antonio J. ^{[1
]}

Fairen-Jimenez, David ^{[2
]}

Salinas-Castillo, Anfonso ^{[3
]}

Lopez-Viseras, Marta E. ^{[1
]}

Rodriguez-Dieguez, Antonio ^{[1
]}

机构：

[1] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[2] Univ Edinburgh, Sch Engn, Inst Mat & Proc, Edinburgh EH8 9YL, Midlothian, Scotland

[3] Univ Granada, Dept Quim Analit, E-18071 Granada, Spain

来源：

POLYHEDRON | 2013年 / 52卷

关键词：

Hydrothermal; MOF; Luminescence properties; Adsorption; UNFORESEEN CHEMICAL REARRANGEMENT; COORDINATION POLYMER; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; HYDROTHERMAL SYNTHESIS; COMPLEX; LIGAND; ASSEMBLIES; EMISSION; DESIGN;

D O I：

10.1016/j.poly.2012.09.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of La(NO3)(3) with 2-pyrimidinecarbonitrile in water yields a 3D metal-organic coordination framework [La-2(ox)(3)(H(2)ox)(H2O)(2)](H2O)(8) (1) (ox = oxalate). This compound has channels with hosted water molecules inside and shows an intense photoluminescence emission at room temperature in the solid state. Due to the great channels that this compound possesses we have analyzed the experimental and simulated adsorption properties. This is one of the few examples of three-dimensional lanthanum polymers based only on oxalate ligand. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：315 / 320

页数：6

共 73 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2]

[Anonymous], 2012, APEX2

[3]

[Anonymous], 1965, PHYS PRINCIPLES MAGN

[4] Intermolecular proton transfer in solid phase: A rare example of crystal-to-crystal transformation from hydroxo- to oxo-bridged iron(III) molecule-based magnet [J].

Armentano, D ;

De Munno, G ;

Mastropietro, TF ;

Julve, M ;

Llore, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (31) :10778-10779

[5] Polymorphism of molecular organometallic crystals.: A third form of the supramolecular hydrogen-bonded dimer {[FeII(η5-C5H4COOH)2]}2 [J].

Braga, D ;

Polito, M ;

D'Addario, D ;

Grepioni, F .

CRYSTAL GROWTH & DESIGN, 2004, 4 (06) :1109-1112

[6] Taking advantage of luminescent lanthanide ions [J].

Bünzli, JCG ;

Piguet, C .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (12) :1048-1077

[7] Homo- and heterometallic coordination polymers from the f elements [J].

Cahill, Christopher L. ;

de Lill, Daniel T. ;

Frisch, Mark .

CRYSTENGCOMM, 2007, 9 (01) :15-26

[8] Polyfunctional inorganic-organic hybrid materials: An unusual kind of NLO active layered mixed metal oxalates with tunable magnetic properties and very large second harmonic generation [J].

Cariati, Elena ;

Macchi, Roberto ;

Roberto, Dominique ;

Ugo, Renato ;

Galli, Simona ;

Casati, Nicola ;

Macchi, Piero ;

Sironi, Angelo ;

Bogani, Lapo ;

Caneschi, Andrea ;

Gatteschi, Dante .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (30) :9410-9420

[9] Lanthanide(III)/Pyrimidine-4,6-dicarboxylate/Oxalate Extended Frameworks: A Detailed Study Based on the Lanthanide Contraction and Temperature Effects [J].

Cepeda, Javier ;

Balda, Rolindes ;

Beobide, Garikoitz ;

Castillo, Oscar ;

Fernandez, Joaquin ;

Luque, Antonio ;

Perez-Yanez, Sonia ;

Roman, Pascual ;

Vallejo-Sanchez, Daniel .

INORGANIC CHEMISTRY, 2011, 50 (17) :8437-8451

[10] Strongly luminescent metal-organic compounds: spectroscopic properties and crystal structure of substituted 1,8-naphthyridine and its zinc(II) complex [J].

Che, CM ;

Wan, CW ;

Ho, KY ;

Zhou, ZY .

NEW JOURNAL OF CHEMISTRY, 2001, 25 (01) :63-65

← 1 2 3 4 5 6 7 8 →