Ionic Liquid-Nanoparticle Hybrid Electrolytes and their Application in Secondary Lithium-Metal Batteries

被引:277
作者
Lu, Yingying [1 ]
Das, Shyamal K. [1 ]
Moganty, Surya S. [1 ]
Archer, Lynden A. [1 ]
机构
[1] Cornell Univ, Sch Chem & Biomol Engn, Ithaca, NY 14853 USA
基金
美国国家科学基金会;
关键词
DENDRITE FORMATION; BIS(TRIFLUOROMETHANESULFONYL)IMIDE; CHALLENGES; DEPOSITION; MECHANISMS; NANOTUBES; GROWTH; CARBON;
D O I
10.1002/adma.201201953
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ionic liquid-tethered nanoparticle hybrid electrolytes comprised of silica nanoparticles densely grafted with imidazolium-based ionic liquid chains are shown to retard lithium dendrite growth in rechargeable batteries with metallic lithium anodes. The electrolytes are demonstrated in full cell studies using both high-energy Li/MoS2 and high-power Li/TiO2 secondary batteries. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4430 / 4435
页数:6
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