Selective hydrosilylation of allyl esters with octahydridosilsesquioxane

被引：16
|
作者：
Igarashi, Masayasu [1 ]
Kobayashi, Toshiaki [1 ]
Sato, Kazuhiko [1 ]
Ando, Wataru [1 ]
Matsumoto, Tomohiro [1 ]
Shimada, Shigeru [1 ]
Hara, Masanao [2 ]
Uchida, Hiroshi [2 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
[2] Showa Denko Co Ltd, Corp R&D Ctr Chiba, Ichihara, Chiba 2900067, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 725卷
关键词：
Hydrosilylation; Octasilsesquioxanes; Allyl esters; Catalysis; Thermosetting resins; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; ORGANIC/INORGANIC HYBRID COMPOSITES; CUBIC SILSESQUIOXANES; EPOXY NANOCOMPOSITES; THERMOMECHANICAL PROPERTIES; CHLORIDE; POSS; TRICHLOROSILANE; MORPHOLOGY; COMPLEXES;
D O I：
10.1016/j.jorganchem.2012.11.028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrosilylation of allyl esters with octahydridosilsesquioxane (T8H8) in the presence of platinum-based catalysts was studied. The effects of the catalysts and the reaction conditions on the conversion and the selectivity of the products were investigated. Karstedt's catalyst with two equivalents of PPh3 was found to be a superior hydrosilylation catalyst in terms of conversion and selectivity, compared with other Pt catalysts examined. An octasilsesquioxane functionalized with epoxy substituents was synthesized using the optimized reaction system, which was converted to a thermosetting polymer and its properties were investigated. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：54 / 59
页数：6
相关论文
共 50 条
  • [31] Analysis on olefin hydrosilylation catalyzed by a cationic nickel allyl complex
    Choe, Yoong-Kee
    Mathew, Jomon
    Nakajima, Yumiko
    Shimada, Shigeru
    Sato, Kazuhiko
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [32] Microwave accelerated selective and facile deprotection of allyl esters catalyzed by Montmorillonite K-10
    Gajare, Anil S.
    Shaikh, Nadim S.
    Bonde, Bhushan K.
    Deshpande, Vishnu H.
    Journal of the Chemical Society, Perkin Transactions 1, 2000, (05): : 639 - 640
  • [33] Nickel-Catalyzed Highly Selective Hydroalkenylation of Alkenyl Boronic Esters to Access Allyl Boron
    Zhang, Penglin
    Zhang, Min
    Ji, Yuqi
    Xing, Mimi
    Zhao, Qian
    Zhang, Chun
    ORGANIC LETTERS, 2020, 22 (21) : 8285 - 8290
  • [34] Rapid and selective deallylation of allyl ethers and esters using iodine in polyethylene glycol-400
    Konda, Shankaraiah G.
    Humne, Vivek T.
    Lokhande, Pradeep D.
    GREEN CHEMISTRY, 2011, 13 (09) : 2354 - 2358
  • [35] Microwave accelerated selective and facile deprotection of allyl esters catalyzed by Montmorillonite K-10
    Gajare, AS
    Shaikh, NS
    Bonde, BK
    Deshpande, VH
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (05): : 639 - 640
  • [36] RUTHENIUM COMPLEX-CATALYZED HYDROSILYLATION OF ALLYL CHLORIDE WITH TRIMETHOXYSILANE
    TANAKA, M
    HAYASHI, T
    MI, ZY
    JOURNAL OF MOLECULAR CATALYSIS, 1993, 81 (02): : 207 - 214
  • [37] Mechanistic insights into the iridium-catalyzed hydrosilylation of allyl compounds
    Riener, Korbinian
    Meister, Teresa K.
    Gigler, Peter
    Herrmann, Wolfgang A.
    Kuehn, Fritz E.
    JOURNAL OF CATALYSIS, 2015, 331 : 203 - 209
  • [38] SYNTHESIS OF ALLYL ESTERS OF NEO ACIDS
    PIROZHKOV, SD
    PUZITSKII, KV
    RYABOVA, KG
    MYSHENKOVA, TN
    EIDUS, YT
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1976, 49 (07): : 1674 - 1675
  • [39] Identification of allyl esters in garlic cheese
    Herbrand, Klaus
    Hammerschmidt, Franz J.
    Brennecke, Stefan
    Liebig, Margit
    Losing, Gerd
    Schmidt, Claus Oliver
    Gatfield, Ian
    Krammer, Gerhard
    Bertram, Heinz-Jurgen
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (19) : 7874 - 7878
  • [40] PHOTOINDUCED BIRCH REDUCTION OF ALLYL ESTERS
    TSUJIMOTO, K
    KAMIYAMA, Y
    FURUKAWA, Y
    OHASHI, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 216 - 216
12345