A 24-Gd nanocapsule with a large magnetocaloric effect

被引：266
|
作者：
Chang, Li-Xian [1 ,2 ,3 ]
Xiong, Gang [1 ,2 ]
Wang, Li [3 ]
Cheng, Peng [1 ,2 ]
Zhao, Bin [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, TKL Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
[3] Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 11期
关键词：
STRUCTURAL-CHARACTERIZATION; COORDINATION CHEMISTRY; MOLECULAR MAGNETS; CLUSTERS; GD; COMPLEXES; LN; POLYNUCLEAR; FRAMEWORKS; COOLERS;
D O I：
10.1039/c2cc35800j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two 24-nuclear lanthanide clusters, Gd-24 and Dy-24 were obtained and structurally characterized. Magnetic investigations reveal that Gd-24 exhibits the largest entropy change (-Delta S-m) of 46.12 J kg(-1) K-1 for Delta H = 7 T in all reported molecular clusters, and single-molecule magnet behaviour is observed in Dy-24.
引用
收藏
页码：1055 / 1057
页数：3
相关论文
共 50 条
  • [31] Theoretical Study of Exchange Coupling in 3d-Gd Complexes: Large Magnetocaloric Effect Systems
    Cremades, Eduard
    Gomez-Coca, Silvia
    Aravena, Daniel
    Alvarez, Santiago
    Ruiz, Eliseo
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (25) : 10532 - 10542
  • [32] {Gd22Ni22}: A double-shell nanocluster exhibits large magnetocaloric effect
    Lu, Zixiu
    Duan, Chunhui
    Wang, Jiaxing
    JOURNAL OF MOLECULAR STRUCTURE, 2024, 1312
  • [33] A novel alb metalloring organic framework with a{Ni12Gd24} cage exhibiting a significant magnetocaloric effect
    Feng, Ya-Nan
    Tian, Chong-Bin
    Du, Shao-Wu
    DALTON TRANSACTIONS, 2017, 46 (31) : 10210 - 10214
  • [34] Large magnetocaloric effect in metamagnetic HoPdAl
    XU ZhiYi & SHEN BaoGen* State Key Laboratory for Magnetism
    Science China(Technological Sciences), 2012, (02) : 445 - 450
  • [35] Large magnetocaloric effect in metamagnetic HoPdAl
    XU ZhiYi SHEN BaoGen State Key Laboratory for MagnetismInstitute of PhysicsChinese Academy of SciencesBeijing China
    Science China(Technological Sciences), 2012, 55 (02) : 445 - 450
  • [36] Large magnetocaloric effect in metamagnetic HoPdAl
    ZhiYi Xu
    BaoGen Shen
    Science China Technological Sciences, 2012, 55 : 445 - 450
  • [37] Large magnetocaloric effect in metamagnetic HoPdAl
    Xu ZhiYi
    Shen BaoGen
    SCIENCE CHINA-TECHNOLOGICAL SCIENCES, 2012, 55 (02) : 445 - 450
  • [38] PHYSICAL MECHANISMS OF LARGE MAGNETOCALORIC EFFECT
    Tishin, A. M.
    1ST INTERNATIONAL CONFERENCE ON MAGNETIC REFRIGERATION AT ROOM TEMPERATURE, 2005, : 47 - 58
  • [39] Influence of Gd purity on giant magnetocaloric effect of Gd-Si-Ge alloys
    Wu, W
    Zhao, P
    Jiang, ZL
    Li, YH
    Zhu, XD
    Zhou, TD
    RARE METAL MATERIALS AND ENGINEERING, 2003, 32 (11) : 962 - 964
  • [40] A Gd-based borate-carbonate framework exhibiting a large magnetocaloric effect at a low magnetic field
    Liu, Bo-Liang
    Xu, Qiao-Fei
    Long, La-Sheng
    Zheng, Lan-Sun
    DALTON TRANSACTIONS, 2021, 50 (37) : 12831 - 12834
12345