A 24-Gd nanocapsule with a large magnetocaloric effect

被引：266
作者：
Chang, Li-Xian [1 ,2 ,3 ]
Xiong, Gang [1 ,2 ]
Wang, Li [3 ]
Cheng, Peng [1 ,2 ]
Zhao, Bin [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, TKL Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
[3] Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 11期
关键词：
STRUCTURAL-CHARACTERIZATION; COORDINATION CHEMISTRY; MOLECULAR MAGNETS; CLUSTERS; GD; COMPLEXES; LN; POLYNUCLEAR; FRAMEWORKS; COOLERS;
D O I：
10.1039/c2cc35800j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two 24-nuclear lanthanide clusters, Gd-24 and Dy-24 were obtained and structurally characterized. Magnetic investigations reveal that Gd-24 exhibits the largest entropy change (-Delta S-m) of 46.12 J kg(-1) K-1 for Delta H = 7 T in all reported molecular clusters, and single-molecule magnet behaviour is observed in Dy-24.
引用
收藏
页码：1055 / 1057
页数：3
相关论文
共 41 条
  • [1] Engineering molecular rings for magnetocaloric effect
    Affronte, M
    Ghirri, A
    Carretta, S
    Amoretti, G
    Piligkos, S
    Timco, GA
    Winpenny, REP
    [J]. APPLIED PHYSICS LETTERS, 2004, 84 (18) : 3468 - 3470
  • [2] A New Family of Nonanuclear Lanthanide Clusters Displaying Magnetic and Optical Properties
    Alexandropoulos, Dimitris I.
    Mukherjee, Shreya
    Papatriantafyllopoulou, Constantina
    Raptopoulou, Catherine P.
    Psycharis, Vassilis
    Bekiari, Vlasoula
    Christou, George
    Stamatatos, Theocharis C.
    [J]. INORGANIC CHEMISTRY, 2011, 50 (22) : 11276 - 11278
  • [3] Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle
    An, Jihyun
    Fiorella, Richard P.
    Geib, Steven J.
    Rosi, Nathaniel L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) : 8401 - +
  • [4] Metal-Controlled Assembly of Near-Infrared-Emitting Pentanuclear Lanthanide β-Diketone Clusters
    Chen, Xiao-Yan
    Yang, Xiaoping
    Holliday, Bradley J.
    [J]. INORGANIC CHEMISTRY, 2010, 49 (06) : 2583 - 2585
  • [5] Tetradecanuclear polycarbonatolanthanoid clusters: Diverse coordination modes of carbonate providing access to novel core geometries
    Chesman, Anthony S. R.
    Turner, David R.
    Moubaraki, Boujemaa
    Murray, Keith S.
    Deacon, Glen B.
    Batten, Stuart R.
    [J]. DALTON TRANSACTIONS, 2012, 41 (36) : 10903 - 10909
  • [6] A trinuclear gadolinium complex:: Structure and magnetic properties
    Costes, JP
    Dahan, F
    Nicodème, F
    [J]. INORGANIC CHEMISTRY, 2001, 40 (20) : 5285 - +
  • [7] Dodecanuclear [Cu6IIGd6III] Nanoclusters as Magnetic Refrigerants
    Dinca, Alina S.
    Ghirri, Alberto
    Madalan, Augustin M.
    Affronte, Marco
    Andruh, Marius
    [J]. INORGANIC CHEMISTRY, 2012, 51 (07) : 3935 - 3937
  • [8] Magnetotherma properties of molecule-based materials
    Evangelisti, M.
    Luis, F.
    de Jongh, L. J.
    Affronte, M.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (26) : 2534 - 2549
  • [9] Evangelisti M., 2011, ANGEW CHEM, V123, P6736
  • [10] Recipes for enhanced molecular cooling
    Evangelisti, Marco
    Brechin, Euan K.
    [J]. DALTON TRANSACTIONS, 2010, 39 (20) : 4672 - 4676
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