Synthesis and characterization of a zirconium complex containing a corannulene-based ligand

被引:16
作者
Chin, RM [1 ]
Jarosh, MS
Russell, JD
Lachicotte, RJ
机构
[1] Univ No Iowa, Dept Chem, Cedar Falls, IA 50614 USA
[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
关键词
D O I
10.1021/om0201765
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Exo-(eta(5)-C20H17)(eta(5)-C5H5)ZrCl2 has been synthesized using partially hydrogenated corannulene as an eta(5)-ligand. The zirconium atom was determined to be bound to the exo face of the bowl-shaped ligand by an X-ray diffraction study.
引用
收藏
页码:2027 / 2029
页数:3
相关论文
共 23 条
[1]  
Alt HG, 1998, CHEM SOC REV, V27, P323
[2]   CORANNULENE REDUCTION - SPECTROSCOPIC DETECTION OF ALL ANIONIC OXIDATION-STATES [J].
BAUMGARTEN, M ;
GHERGHEL, L ;
WAGNER, M ;
WEITZ, A ;
RABINOVITZ, M ;
CHENG, PC ;
SCOTT, LT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (23) :6254-6257
[3]   SYNTHESIS AND DYNAMICS OF THE CORANNULENE NUCLEUS [J].
BORCHARDT, A ;
FUCHICELLO, A ;
KILWAY, KV ;
BALDRIDGE, KK ;
SIEGEL, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (05) :1921-1923
[4]   PI-ORBITAL CONJUGATION AND REHYBRIDIZATION IN BRIDGED ANNULENES AND DEFORMED MOLECULES IN GENERAL - PI-ORBITAL AXIS VECTOR ANALYSIS [J].
HADDON, RC ;
SCOTT, LT .
PURE AND APPLIED CHEMISTRY, 1986, 58 (01) :137-142
[6]   Synthetic studies directed towards bucky-balls and bucky-bowls [J].
Mehta, G ;
Rao, HSP .
TETRAHEDRON, 1998, 54 (44) :13325-13370
[7]   Embracing C60 with multiarmed geodesic partners [J].
Mizyed, S ;
Georghiou, PE ;
Bancu, M ;
Cuadra, B ;
Rai, AK ;
Cheng, PC ;
Scott, LT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (51) :12770-12774
[8]   Buckybowls: Polynuclear aromatic hydrocarbons related to the buckminsterfullerene surface [J].
Rabideau, PW ;
Sygula, A .
ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (05) :235-242
[9]   CONCERNING THE STRUCTURE OF THE CORANNULENE TETRAANION [J].
RABIDEAU, PW ;
MARCINOW, Z ;
SYGULA, R ;
SYGULA, A .
TETRAHEDRON LETTERS, 1993, 34 (40) :6351-6354
[10]   Half-sandwich metallocene embedded in a spherically extended π-conjugate system.: Synthesis, structure, and electrochemistry of Rh(η5-C60Me5)(CO)2 [J].
Sawamura, M ;
Kuninobu, Y ;
Nakamura, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (49) :12407-12408