Potassium tert-Butoxide Mediated Reductive C-P Cross-Coupling of Arylvinyl Sulfides through C-S Bond Cleavage

被引：4
作者：
Feng, Jie [1 ]
Zhang, Qiaoling [1 ]
Li, Fuhai [1 ]
Yang, Lu [2 ]
Kuchukulla, Ratnakar Reddy [1 ]
Zeng, Qingle [1 ]
机构：
[1] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, State Key Lab Geohazard Prevent & Geoenvironm Pro, Chengdu 610059, Peoples R China
[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, 6-3 Azaaoba Aramaki, Sendai, Miyagi 9808578, Japan
来源：
SYNLETT | 2021年 / 32卷 / 02期
关键词：
alkenyl sulfides; C-S bond cleavage; C-P bond formation; potassium butoxide; transition-metal-free synthesis; STEREOSELECTIVE-SYNTHESIS; NICKEL CATALYSIS; OXIDES; HYDROPHOSPHINYLATION; CONSTRUCTION; SULFOXIMINES; ACTIVATION; SULFONES; AMINES; ACIDS;
D O I：
10.1055/s-0040-1707319
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A transition-metal-freet-BuOK-mediated reductive C-P cross-coupling reaction of arylvinyl sulfides with diarylphosphine oxides through C-S bond cleavage has been developed. This protocol not only permits the synthesis of diaryl(2-arylethyl)phosphine oxides, but also achieves an unprecedented construction of a C-P bond through C-S bond cleavage and reduction of a C-C double bond in one pot.
引用
收藏
页码：224 / 228
页数：5
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