The solid state reaction of CuCl2 center dot 2H(2)O and 8-hydroxylquinoline

被引：7
作者：
Lei, LX
Wang, ZX
Xin, XQ
机构：
[1] CHINA PHARMACEUT UNIV,SCH PHARM,NANJING 210009,PEOPLES R CHINA
[2] NANJING UNIV,DEPT CHEM,NANJING 210093,PEOPLES R CHINA
来源：
THERMOCHIMICA ACTA | 1997年 / 297卷 / 1-2期
关键词：
DSC; mechanism; reaction; solid; XRD;
D O I：
10.1016/S0040-6031(97)00144-5
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
CuCl2 . 2H(2)O reacts with 8-hydroxylquinoline (short as HQ) in two steps if the reactants are mixed in 1 : 2 molar ratio: first, it produces a new intermediate, Cu(HQ)Cl-2, and then the intermediate reacts with free 8-hydroxylquinoline and produces CuQCl. However, the same reactants can only give CuQCl or CuQ(2) in the methanol solution. Reasons that lead to those results are discussed. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：193 / 197
页数：5
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