Organopalladium Complexes of Oxacalixarenes: Selecting the Lid for the Three-Dimensional Scaffold

被引：7

作者：

Visitaev, Yulia ^{[1
]}

Goldberg, Israel ^{[1
]}

Vigalok, Arkadi ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 12期

基金：

以色列科学基金会;

关键词：

CALIXARENE; CHEMISTRY;

D O I：

10.1021/ic400925y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first organometallic (palladium) complexes of oxacalixarene molecules were prepared via oxidative addition of the C-I bond at the lower rim. The unique geometry of the oxacalixarene scaffold allowed for the selective introduction of new ligands at the top of the calixarene scaffold. Such coordination can be used to coordinatively link the opposing aromatic rings.

引用

页码：6779 / 6781

页数：3

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