Phenylvinylidene RePt Complexes Containing Diphenylphosphine Ligands at the Platinum Atom: Synthesis, IR, NMR Spectroscopic and Electrochemical Properties

被引：0

作者：

Chudin, Oleg S. ^{[1
]}

Verpekin, Victor V. ^{[1
]}

Burmakina, Galina, V ^{[1
]}

Zimonin, Dmitry, V ^{[1
]}

Kondrasenko, Alexander A. ^{[1
]}

Rubaylo, Anatoly, I ^{[1
]}

机构：

[1] FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia

来源：

JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2020年 / 13卷 / 03期

关键词：

electrochemistry; redox properties; binuclear complexes; phenylvinylidene; rhenium; platinum; carbonyl; diphenylphosphine; CHEMISTRY; MNPT; REACTIVITY; CLUSTERS; CORE;

D O I：

10.17516/1998-2836-0191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mu-phenylvinylidene complexes Cp(CO)(2)RePt(mu-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri) 3 (2)] were synthesized for the first time. Their IR, NMR spectroscopic and redox properties were studied. Based on IR, NMR spectroscopic data their molecular structures were proposed. The pathways of redox-reactions of the complexes were determined.

引用

页码：385 / 394

页数：10

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