Palladium(IV) in an Oxoanionic Environment: The XeF2 Assisted Synthesis of [Pd(S2O7)3]2-

被引：10

作者：

Bruns, Joern ^{[1
]}

van Gerven, David ^{[2
]}

Kluener, Thorsten ^{[3
]}

Wickleder, Mathias S. ^{[2
]}

机构：

[1] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria

[2] Justus Liebig Univ Giessen, Inst Anorgan & Analyt Chem, Heinrich Buff Ring 17, D-35392 Giessen, Germany

[3] Carl von Ossietzky Univ Oldenburg, Inst Chem, Carl von Ossietzky Str 9-11, D-26129 Oldenburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 28期

关键词：

density functional theory; disulfate; palladium; structure elucidation; vibrational spectroscopy; CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; CRYSTAL-STRUCTURE; FLUORIDES; SULFATE; ATOMS; GROUP-11; TI;

D O I：

10.1002/anie.201601767

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time tetravalent palladium is detected, coordinated exclusively by simple oxoanions. Stabilization was achieved by formation of the [Pd(S2O7)(3)](2-) complex in which three chelating disulfate groups surround the metal atom. The salt K-2[Pd(S2O7)(3)] could only be obtained if the reaction of K-2[PdCl6] and neat SO3 was performed in the presence of XeF2.

引用

收藏

页码：8121 / 8124

页数：4

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