Study of hydrogen supply system with ammonia fuel

被引:18
作者
Saika, T
Nakamura, M
Nohara, T
Ishimatsu, S
机构
[1] Kogakuin Univ, Fac Engn, Dept Basic Engn Global Environm, Hachioji, Tokyo 1920015, Japan
[2] Kogakuin Univ, Fac Engn, Dept Mech Syst Design, Hachioji, Tokyo 1920015, Japan
[3] Hitachi Ltd, Chiyoda Ku, Tokyo 1008280, Japan
[4] Kogakuin Univ, Grad Sch, Grad Course Mech Engn, Shinjuku Ku, Tokyo 1638677, Japan
关键词
global warming; hydrogen; ammonia; alternate fuel; ammonia dissociation; fuel cell;
D O I
10.1299/jsmeb.49.78
中图分类号
O414.1 [热力学];
学科分类号
摘要
Carbon-free fuel is effective in preventing global warming. Hydrogen has no carbon and can be made also from nuclear energy or reproducible energies other than fossil fuels. However, hydrogen lacks portability because of its difficulty in liquefying, but ammonia can easily be liquefied at a room temperature and dissociated into high-content hydrogen and nitrogen using a suitable catalyst. An ammonia dissociation system for fuel cells is proposed in this paper. The residual ammonia by 13 ppm or more in the dissociated gas (H-2 + N-2) causes a decrease in the output of fuel cells. To separate residual ammonia, it should be sent to an ammonia separator and then to an ammonia distiller. In the experiment, the authors examine the concentrations of ammonia after dissociation at various temperatures, pressures and space velocities. The ammonia separator uses the fact that ammonia dissolves well in water. Then the ammonia water is distilled in the distiller. Thereby, the authors have proposed an ammonia circulation system that is a clean energy system.
引用
收藏
页码:78 / 83
页数:6
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