Iron corroles and porphyrins as very efficient and highly selective catalysts for the reactions of α-diazo esters with amines

被引：60

作者：

Aviv, I

Gross, Z ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

SYNLETT | 2006年 / 06期

关键词：

diazo compounds; iron; corroles; porphyrins; catalysis;

D O I：

10.1055/s-2006-939035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iron corroles and porphyrins catalyze the reactions of amines with ethyl diazoacetate extremely efficiently, leading to complete and rapid conversion into N-substituted glycine ethyl esters by simultaneous addition of the Substrates to the catalysts. The selectivity toward activation of the NH bonds is remarkable and quite different from other catalysts.

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收藏

页码：951 / 953

页数：3

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