Synthesis of Li3Cu2SbO6, a new partially ordered rock salt structure

被引：43

作者：

Skakle, JMS ^{[1
]}

Castellanos, MA ^{[1
]}

Tovar, ST ^{[1
]}

West, AR ^{[1
]}

机构：

[1] UNIV NACL AUTONOMA MEXICO,FAC QUIM,MEXICO CITY 04510,DF,MEXICO

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1997年 / 131卷 / 01期

关键词：

D O I：

10.1006/jssc.1997.7356

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new phase Li3Cu2SbO6, synthesised by solid state reaction at 1000 degrees C, is monoclinic, a=5.4659(1), b=8.7272(2), c=9.7807(3) Angstrom, beta=95.080(2)degrees, space group C2/c, and has a partially ordered rock salt structure related to the ordered structure of Li2TiO3 by additional cation order: Ti sites are occupied by Cu and Sb in ordered fashion; Li sites contain Li/Cu in two sets, but with nonstatistical occupancy, and Li. Bond lengths show a Jahn-Teller elongation of CuO6 octahedra consistent with magnetic susceptibility data that indicate paramagnetic Cu2+ ions. Li3Cu2SbO6 shows a low level of electronic conductivity. (C) 1997 Academic Press.

引用

页码：115 / 120

页数：6

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