A Mn5II tetragonal pyramid stabilized by p-tert-butylcalix[8]arene: Synthesis, structure and magnetic property

被引：8
作者：
Du, Shangchao [1 ,2 ]
Ke, Hongshan [1 ]
Bi, Yanfeng [1 ]
Tan, Huaqiao [1 ]
Yu, Yang [1 ]
Tang, Jinkui [1 ]
Liao, Wuping [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 29卷
基金：
中国国家自然科学基金;
关键词：
Calixarenes; Manganese; Magnetic property; Crystal growth; Solvothermal synthesis; TETRANUCLEAR MANGANESE(II) COMPLEXES; CLUSTER COMPLEXES; COORDINATION CHEMISTRY; METAL; LIGAND; CONSTRUCTION; MACROCYCLES; CALIXARENES; BOND;
D O I：
10.1016/j.inoche.2012.12.021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A compound, [Mn-5(H(4)C8A)(OH)(2)(C3H6NO2)(DMF)(5)(CH3O)(1.5)(HCO2) (C2H3O2)(0.5)] center dot 2DMF center dot CH3OH (1) (H(8)C8A = p-tert-butylcalix[8]arene, DMF = N,N'-dimethylformamide), was synthesized by the solvothermal method in the mixed CH3OH/DMF (1:1) solvent. Compound 1 is featured with a tetragonal pyramid-like Mn-5(II) cluster encircled within a calix[8]arene molecule with a 'pleated loop' conformation. Magnetic study indicates that the Mn-II centers exhibit antiferromagnetic interactions. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：85 / 88
页数：4
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