Capsules, cages and three-dimensional hosts: Self-assembly of complementary monomers

被引:22
作者
Johnston, MR [1 ]
Latter, MJ [1 ]
机构
[1] Flinders Univ S Australia, Sch Chem Phys & Earth Sci, Bedford Pk, SA 5042, Australia
关键词
molecular capsules; metal ion coordination cages; three-dimensional hosts; guest encapsulation; self-assembly;
D O I
10.1080/10610270500128400
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecular capsules, cages and other three-dimensional hosts arising from the reversible assembly of complementary monomers are able to enclose space and encapsulate guest molecules. This article highlights work done in this area exemplifying the growing variety of non-covalent stabilising interactions being employed in host formation. These interactions include hydrogen bonding, ionic interactions, metal ion coordination as well as combinations thereof. Due to the protective environment offered by these hosts from the bulk phase solution, altered properties are often observed for encapsulated guests which is paving the way towards realising practical applications of such host systems.
引用
收藏
页码:595 / 607
页数:13
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