Synthesis and photoluminescence properties of self-assembled Eu-doped ZnO hollow microspheres

被引：7

作者：

Xu, Jin ^{[1
,2
]}

Wang, Nating ^{[1
]}

Wang, Weiqiang ^{[1
]}

机构：

[1] Xiamen Univ, Coll Mat, Dept Mat Sci & Engn, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Key Lab Fire Retardant Mat Fujian Prov, Xiamen 361005, Peoples R China

来源：

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2011年 / 208卷 / 12期

基金：

中国国家自然科学基金;

关键词：

photoluminescence; solvothermal; transmission electron microscopy; ZnO:Eu3+; EFFICIENT ENERGY-TRANSFER; ZINC-OXIDE; HYDROTHERMAL SYNTHESIS; OPTICAL-PROPERTIES; ROOM-TEMPERATURE; EU3+-DOPED ZNO; NANOCRYSTALS; SPHERES; NANOSTRUCTURES; ARCHITECTURES;

D O I：

10.1002/pssa.201127290

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

ZnO hollow microspheres with a shell wall consisting of crystalline ZnO nanosheets were synthesized by using Zn5(CO3)2(OH)6 microspheres as spherical templates. Zn5(CO3)2(OH)6 microspheres were first fabricated by a solvothermal procedure in an ethylene glycol (EG)water solution. ZnO microspheres with a hexagonal structure were identified by means of X-ray diffraction (XRD) and selected-area electron diffraction (SAED). On the basis of the results, a possible self-assembly growth mechanism was proposed. It reveals that the EG played an important role in determining the hollow morphologies of Zn5(CO3)2(OH)6 structures. In addition, photoluminescence (PL) investigation of ZnO:Eu3+ suggested that a direct energy transfer occurred, which was ascribed to the energy transfer from ZnO host to Eu3+ ions.

引用

页码：2833 / 2838

页数：6

共 32 条

[1] Polystyrene-ZnO composite particles with controlled morphology [J].

Agrawal, Mukesh ;

Pich, Andrij ;

Zafeiropoulos, Nick E. ;

Gupta, Smrati ;

Pionteck, Juergen ;

Simon, Frank ;

Stamm, Manfred .

CHEMISTRY OF MATERIALS, 2007, 19 (07) :1845-1852

[2] Controlled growth and properties of one-dimensional ZnO nanostructures with Ce as activator/dopant [J].

Cheng, BC ;

Xiao, YH ;

Wu, GS ;

Zhang, LD .

ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (09) :913-919

[3] Hybrid ZnO-Dye hollow spheres with new optical properties from a self-assembly process based on Evans blue dye and cetyltrimethylammonium bromide [J].

Cong, Huai-Ping ;

Yu, Shu-Hong .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (11) :1814-1820

[4] Efficient energy transfer in monodisperse Eu-doped ZnO nanocrystals synthesized from metal acetylacetonates in high-boiling solvents [J].

Du, Ya-Ping ;

Zhang, Ya-Wen ;

Sun, Ling-Dong ;

Yan, Chun-Hua .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (32) :12234-12241

[5] Synthesis of hollow ZnO microspheres by an integrated autoclave and pyrolysis process [J].

Duan, JX ;

Huang, XT ;

Wang, EK ;

Ai, HH .

NANOTECHNOLOGY, 2006, 17 (06) :1786-1790

[6] Doping semiconductor nanocrystals [J].

Erwin, SC ;

Zu, LJ ;

Haftel, MI ;

Efros, AL ;

Kennedy, TA ;

Norris, DJ .

NATURE, 2005, 436 (7047) :91-94

[7] Engineering white light-emitting Eu-doped ZnO urchins by biopolymer-assisted hydrothermal method [J].

Gao, Shuyan ;

Zhang, Hongjie ;

Deng, Ruiping ;

Wang, Xiaomei ;

Sun, Dehui ;

Zheng, Guoli .

APPLIED PHYSICS LETTERS, 2006, 89 (12)

[8] The fabrication of an upright-standing zinc oxide nanosheet for use in dye-sensitized solar cells [J].

Hosono, E ;

Fujihara, S ;

Honna, I ;

Zhou, HS .

ADVANCED MATERIALS, 2005, 17 (17) :2091-+

[9] Structural and luminescence properties of Eu-doped ZnO nanorods fabricated by a microemulsion method [J].

Ishizumi, A ;

Kanemitsu, Y .

APPLIED PHYSICS LETTERS, 2005, 86 (25) :1-3

[10] Photoluminescence dependence of ZnO films grown on Si(100) by radio-frequency magnetron sputtering on the growth ambient [J].

Jeong, SH ;

Kim, BS ;

Lee, BT .

APPLIED PHYSICS LETTERS, 2003, 82 (16) :2625-2627

← 1 2 3 4 →