High axial coordination in a cis-coordinated succinimidatocopper(II) complex

被引：7

作者：

Akitsu, T ^{[1
]}

Komorita, S ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Suita, Osaka 5600043, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2002年 / 75卷 / 04期

关键词：

D O I：

10.1246/bcsj.75.767

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper(II) complex [Cu(succim)(2)(N-Eten)(H2O)(2)] (succim = succinimidate and N-Eten = N-ethylethylenediamine) was prepared and characterized by X-ray crystallography and polarized crystal electronic spectra. The complex has a distorted octahedral [CuN4O2] chromophore. The pi-donor succim ligands on cis-positions raise the potential of axial coordination up to six-coordination to maintain electroneutrality of the complex.

引用

页码：767 / 768

页数：2

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