Photocatalytic degradation of methylene blue with Fe doped ZnS nanoparticles

被引：72

作者：

Chauhan, Ruby ^{[1
]}

Kumar, Ashavani ^{[2
]}

Chaudhary, Ram Pal ^{[1
]}

机构：

[1] Sant Longowal Inst Engg & Tech, Dept Chem, Longowal 148106, India

[2] Natl Inst Technol, Dept Phys, Kurukshetra 136119, Haryana, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2013年 / 113卷

关键词：

Nanoparticle; Scanning electron microscope; Transmission electron microscope; Photocatalysis; TIO2; WATER; 2-CHLOROBIPHENYL; KINETICS;

D O I：

10.1016/j.saa.2013.04.087

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Fe doped ZnS nanoparticles (Zn1-xFexS; where x = 0.00, 0.03, 0.05 and 0.10) were synthesized by a chemical precipitation method. The synthesized products were characterized by X-ray diffraction, scanning electron microscope, transmission electron microscope, UV-Vis and photoluminescence spectrometer. The X-ray diffraction and transmission electron microscope studies show that the size of crystallites is in the range of 2-5 nm. Photocatalytic activities of ZnS and 3,5 and 10 mol% Fe doped ZnS were evaluated by decolorization of methylene blue in aqueous solution under ultraviolet and visible light irradiation. It was found that the Fe doped ZnS bleaches methylene blue much faster than the undoped ZnS upon its exposure to the visible light as compared to ultraviolet light. The optimal Fe/Zn ratio was observed to be 3 mol% for photocatalytic applications. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：250 / 256

页数：7

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