Switched role of fullerene in the Diels-Alder reaction: facile addition of dienophiles to the conjugated fullerene diene moiety

被引：17

作者：

Yao, Jiayao ^{[1
]}

Xiao, Zuo ^{[1
]}

Zhang, Jianxin ^{[1
]}

Yang, Xiaobing ^{[1
]}

Gan, Liangbing ^{[1
,2
]}

Zhang, Wen-Xiong ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 04期

关键词：

X-RAY STRUCTURES; 4+2 CYCLOADDITIONS; MIXED PEROXIDES; C-60; ADDUCTS; BUCKMINSTERFULLERENE; FUNCTIONALIZATION; ELECTROCHEMISTRY; STEREOCHEMISTRY; DERIVATIVES;

D O I：

10.1039/b817300a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isolated cyclopentadiene moiety in a fullerene multi-adduct derivative reacts readily with dienophiles to form [4 + 2] cycloaddition products.

引用

页码：401 / 403

页数：3

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