Polyaniline Composites for Chemical Sensors and Release Devices

被引:3
作者
Bouhadid, Myriam [1 ,2 ]
Thevenot, Caroline [1 ]
Ehrenfeld, Francis [1 ]
Redon, Nathalie [2 ]
Desbrieres, Jacques [1 ]
Grassl, Bruno [1 ]
Reynaud, Stephanie [1 ]
机构
[1] EPCP, IPREM, UMR 5254, F-64953 Pau 9, France
[2] Ecole Mines Douai, F-59508 Douai, France
关键词
Polyaniline Sensors; Conducting Hydrogels; Conducting Polymer Synthesis; Controlled Release;
D O I
10.1166/sl.2008.428
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This study is based on the synthesis of composite particles made of polymer matrix and of intrinsically conducting polymer (ICP), with architecture control. Particle dispersion has been deposited on glass or plastic substrate to form a conducting film. This film has been successfully tested in sensor devices, namely gas sensors and electro-controlled delivery systems. In the first application, films have been performed and tested as active layer for ammonia detection. This chemical sensor template has been optimized in term of chemical composition and properties. These new sensors are sensitive (a pollution as low as 10 ppm ammonia is detected), exhibit a short response time (few seconds) and may be used several times in a row with the same performances. In the second application, core-shell particles have been entrapped into a hydrogel and these hydrogel composites have been characterized by polymerization kinetics, morphological, rheological, and swelling studies. These composites have been then evaluated as potentially drug release templates under electric field.
引用
收藏
页码:548 / 557
页数:10
相关论文
共 29 条
[21]   Use of polymeric emeraldine salt for conductive adhesive applications [J].
Sancaktar, E ;
Liu, CJ .
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2003, 17 (09) :1265-1282
[22]   Prospects of conducting polymers in molecular electronics [J].
Saxena, V ;
Malhotra, BD .
CURRENT APPLIED PHYSICS, 2003, 3 (2-3) :293-305
[23]   Conducting polymer gel: formation of a novel semi-IPN from polyaniline and crosslinked poly (2-acrylamido-2-methyl propanesulphonicacid) [J].
Siddhanta, SK ;
Gangopadhyay, R .
POLYMER, 2005, 46 (09) :2993-3000
[24]   Responsive conducting polymer-hydrogel composites [J].
Small, CJ ;
Too, CO ;
Wallace, GG .
POLYMER GELS AND NETWORKS, 1997, 5 (03) :251-265
[25]   Polyaniline. Preparation of a conducting polymer (IUPAC technical report) [J].
Stejskal, J ;
Gilbert, RG .
PURE AND APPLIED CHEMISTRY, 2002, 74 (05) :857-867
[26]   Kinetic aspects, rheological properties and mechanoelectrical effects of hydrogels composed of polyacrylamide and polystyrene nanoparticles [J].
Thevenot, Caroline ;
Khoukh, Abdel ;
Reynaud, Stephanie ;
Desbrieres, Jacques ;
Grassl, Bruno .
SOFT MATTER, 2007, 3 (04) :437-447
[27]   Molecular recognition solvents for electrically conductive polyaniline [J].
Vikki, T ;
Pietila, LO ;
Osterholm, H ;
Ahjopalo, L ;
Takala, A ;
Toivo, A ;
Levon, K ;
Passiniemi, P ;
Ikkala, O .
MACROMOLECULES, 1996, 29 (08) :2945-2953
[28]   Novel conducting polymer-polyelectrolyte composites [J].
Wallace, GG ;
Zhao, H ;
Too, CO ;
Small, CJ .
SYNTHETIC METALS, 1997, 84 (1-3) :323-326
[29]   Intrinsic viscosity measurement of dilute emeraldine base solutions for estimating the weight average molecular weight of polyaniline [J].
Yang, DL ;
Adams, PN ;
Mattes, BR .
SYNTHETIC METALS, 2001, 119 (1-3) :301-302