Coordination polymers based on aluminum(III) porphyrins

被引：33

作者：

Davidson, Gregory J. E. ^{[1
]}

Lane, Laura A. ^{[2
]}

Raithby, Paul R. ^{[3
,4
]}

Warren, John E. ^{[4
]}

Robinson, Carol V. ^{[2
]}

Sanders, Jeremy K. M. ^{[2
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, Cambs, England

[3] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[4] CCLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 19期

基金：

加拿大自然科学与工程研究理事会; 英国科学技术设施理事会; 英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ic800587y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by H-1 NMR spectroscopy and nanoelectrospray ionization spectrometry. X-ray analyses confirmed the formation of the 1-D polymers in the solid state.

引用

页码：8721 / 8726

页数：6

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