Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

被引：119
作者：
Luo, Jie
Zhu, Zechen
Liu, Yannan
Zhao, Xiaodan [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Inst Organ Chem, Guangzhou 510275, Guangdong, Peoples R China
来源：
ORGANIC LETTERS | 2015年 / 17卷 / 14期
关键词：
C-H BONDS; HYPERVALENT IODONIUM YLIDE; ALPHA-FLUORINATED ETHERS; ELECTROPHILIC TRIFLUOROMETHANESULFANYLATION; OXIDATIVE TRIFLUOROMETHYLTHIOLATION; SILVER(I) TRIFLUOROMETHANETHIOLATE; SUBSTITUENT CONSTANTS; UNACTIVATED ALKENES; MEDICINAL CHEMISTRY; TERMINAL ALKYNES;
D O I：
10.1021/acs.orglett.5b01727
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient approach to vicinal trifluoromethylthioamination of alkenes with a broad substrate scope catalyzed by electronrich diaryl selenide has been developed. This intermolecular amination strategy was successfully applied to SCF3-esterification of alkenes using weak acids as nucleophiles.
引用
收藏
页码：3620 / 3623
页数：4
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