Improvement of Poly(vinyl alcohol) Properties by the Addition of Magnesium Nitrate

被引：27

作者：

Kubo, Jun-ichi ^{[2
]}

Rahman, Nelly ^{[1
]}

Takahashi, Nobuaki ^{[3
]}

Kawai, Takahiko ^{[1
,4
]}

Matsuba, Go ^{[1
]}

Nishida, Koji ^{[1
]}

Kanaya, Toshiji ^{[1
]}

Yamamoto, Masahide ^{[5
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Ako Kasei Co Ltd, Ako, Hyogo 6780193, Japan

[3] J PARC Ctr, Div Mat & Life Sci, Naka, Ibaraki 3191195, Japan

[4] Gunma Univ, Grad Sch Engn, Div Prod Sci & Technol, Kiryu, Gunma 3768515, Japan

[5] Ritsumeikan Univ, Coll Sci & Engn, Kusatsu, Shiga 5258577, Japan

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2009年 / 112卷 / 03期

关键词：

poly(vinyl alcohol); magnesium nitrate hexahydrate; softening; WAXD; SAXS; POLYVINYL-ALCOHOL); GELS;

D O I：

10.1002/app.29561

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aiming at the improvement of mechanical and dielectric properties of poly(vinyl alcohol) (PVA), we prepared composites of PVA and magnesium nitrate hexahydrate. It was found that the composites were very soft and rubber-like, and the glass transition temperature decreased with increasing the salt concentration. Wide-angle X-ray diffraction and small-angle X-ray scattering revealed that the crystallites of PVA were destroyed by the additive and it was the cause of the softening. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 1647-1652, 2009

引用

页码：1647 / 1652

页数：6

共 18 条

[1] X-RAY LINE BROADENING IN ISOTACTIC POLYSTYRENE [J].