Zn based nanoparticle-carbon nanotube hybrid materials: Interaction and charge transfer

被引:7
作者
El Mel, Abdel-Aziz [1 ]
Buffiere, Marie [2 ,3 ]
Ewels, Chris P. [4 ]
Molina-Luna, Leopoldo [5 ]
Faulques, Eric [4 ]
Colomer, Jean-Francois [6 ]
Kleebe, Hans-Joachim [5 ]
Konstantinidis, Stephanos [1 ]
Snyders, Rony [1 ,7 ]
Bittencourt, Carla [1 ]
机构
[1] Univ Mons, Chim Interact Plasma Surface ChIPS, CIRMAP, Res Inst Mat Sci & Engn, B-7000 Mons, Belgium
[2] Katholieke Univ Leuven, Dept Elect Engn, B-3001 Heverlee, Belgium
[3] IMEC, B-3001 Heverlee, Belgium
[4] Univ Nantes, Inst Mat Jean Rouxel, CNRS, UMR 6502, F-44322 Nantes 3, France
[5] Tech Univ Darmstadt, Dept Mat & Geosci, D-64287 Darmstadt, Germany
[6] Univ Namur, Res Ctr Phys Matter & Radiat, Namur, Belgium
[7] Mat Nova Res Ctr, B-7000 Mons, Belgium
关键词
ELECTRONIC-STRUCTURE; OXIDE NANOPARTICLES; KIRKENDALL; ZINC; DIFFUSION; PERFORMANCE; INTERFACE; COMPOSITE; OXIDATION; BEHAVIOR;
D O I
10.1016/j.carbon.2013.09.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The interaction and charge transfer between Zn-based nanoparticles (NPs) and carbon nanotubes (CNTs) is investigated by X-ray Auger and photoelectron spectroscopy. Charge transfer from Zn NPs toward the CNTs is demonstrated by the presence of an additional feature revealed in the C 1s spectrum of CNTs. This charge transfer was found to vanish after thermal oxidation due to the transformation of the metal Zn into ZnO. Photoluminescence (PL) spectroscopy shows that in the samples ZnO(Nps)/CNTs the PL intensity is quenched. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:442 / 449
页数:8
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