N,N′-bis(2-tosylaminobenzylidene)-1,3-propanediamine

被引:21
作者
Mahía, J
Maestro, MA
Vázquez, M
Bermejo, MR
Sanmartín, J
Maneiro, M
机构
[1] Univ A Coruna, Serv Xerais Apoio Invest, E-15071 La Coruna, Spain
[2] Univ Santiago de Compostela, Fac Quim, Dept Quim Inorgan, E-15706 Santiago De Compostela, A Coruna, Spain
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1999年 / 55卷
关键词
D O I
10.1107/S010827019900685X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The conformation of the title molecule, C(31)H(32)N(4)O(4)S2(,) in the solid state is strongly influenced by intramolecular hydrogen-bond interactions (N-H ... N), which probably minimize the steric hindrance of the tosyl groups. The molecule is not planar and with long distances between aminic N atoms [7.724(3) Angstrom], a major change in conformation will be required for it to act as a tecradentate ligand via its four N atoms.
引用
收藏
页码:1545 / 1547
页数:3
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