Hydrogen enrichment of methane and syngas for MILD combustion

被引:81
作者
Mardani, Amir [1 ]
Mahalegi, Hamed Karimi Motaalegh [1 ]
机构
[1] Sharif Univ Technol, Tehran 1458889694, Iran
关键词
MILD combustion; Hydrogen; Syngas; Dilution; Non-premixed turbulent; combustion; EDDY DISSIPATION CONCEPT; NOX FORMATION; JET FLAMES; DIFFUSION FLAMES; BLENDED FLAME; CHEMISTRY; OXYGEN; HOT; IGNITION; MODEL;
D O I
10.1016/j.ijhydene.2019.02.072
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Moderate or Intense Low-oxygen Dilution (MILD) combustion is a technology with important characteristics such as significant low emission and high-efficiency combustion. The hydrogen enrichment of conventional fuels is also of interest due to its favorable characteristics, such as low carbon-containing pollutants, high reaction intensity, high flammability, and thus fuel usage flexibility. In this study, the effects of adding hydrogen to methane and syngas fuels have been investigated under conditions of MILD combustion through numerical simulation of a well-set-up MILD burner. The Reynolds-Averaged Navier-Stokes (RANS) approach is adopted along the Eddy Dissipation Concept (EDC) combustion model with two different chemical mechanisms. Molecular diffusion is modeled using the differential diffusion approach. The effects of oxidizer dilution and fuel jet Reynolds number on the reactive flow field have been studied. Results show that with an increase in hydrogen portion of the fuel mixtures, the volume of the high-temperature region of combustion field increases whereas a reduction of oxidizer oxygen content leads to more proximity to the MILD condition. Increasing the fuel jet Reynolds number will result in an expansion of the combustion zone and shifting of this region in the axial direction. Predictions revealed that the methane flame is more sensitive to the oxidizer dilution and fuel jet Reynolds number than syngas. Moreover, enrichment of fuel with hydrogen seems to be better for acquiring condition of the MILD combustion for syngas rather than methane. Indeed, syngas shows more sensitivity to hydrogen enrichment than methane, which makes hydrogen a good additive to syngas in terms of MILD condition benefits. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:9423 / 9437
页数:15
相关论文
共 65 条
  • [1] Development of a novel flamelet-based model to include preferential diffusion effects in autoignition of CH4/H2 flames
    Abtahizadeh, Ebrahim
    de Goey, Philip
    van Oijen, Jeroen
    [J]. COMBUSTION AND FLAME, 2015, 162 (11) : 4358 - 4369
  • [2] Characteristics of H2-enriched CH4-O2 diffusion flames in a swirl-stabilized gas turbine combustor: Experimental and numerical study
    Aliyu, Mansur
    Nemitallah, Medhat A.
    Said, Syed A.
    Habib, Mohamed A.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (44) : 20418 - 20432
  • [3] Extended EDC local extinction model accounting finite-rate chemistry for MILD combustion
    Aminian, Javad
    Galletti, Chiara
    Tognotti, Leonardo
    [J]. FUEL, 2016, 165 : 123 - 133
  • [4] Numerical Investigation of a MILD Combustion Burner: Analysis of Mixing Field, Chemical Kinetics and Turbulence-Chemistry Interaction
    Aminian, Javad
    Galletti, Chiara
    Shahhosseini, Shahrokh
    Tognotti, Leonardo
    [J]. FLOW TURBULENCE AND COMBUSTION, 2012, 88 (04) : 597 - 623
  • [5] [Anonymous], GRI-Mech 3(0)
  • [6] NOx formation in post-flame gases from syngas/air combustion at atmospheric pressure
    Asgari, Nazli
    Ahmed, Sheikh F.
    Farouk, Tanvir I.
    Padak, Bihter
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (38) : 24569 - 24579
  • [7] ON REDUCED MECHANISMS FOR METHANE AIR COMBUSTION IN NONPREMIXED FLAMES
    BILGER, RW
    STARNER, SH
    KEE, RJ
    [J]. COMBUSTION AND FLAME, 1990, 80 (02) : 135 - 149
  • [8] Control of methane flame properties by hydrogen fuel addition: Application to power plant combustion chamber
    Bouras, Fethi
    Attia, Mohammed El Hadi
    Khaldi, Fouad
    Si-Ameur, Mohammed
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (13) : 8932 - 8939
  • [9] Mild combustion
    Cavaliere, A
    de Joannon, M
    [J]. PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2004, 30 (04) : 329 - 366
  • [10] Syngas combustion kinetics and applications
    Chaos, Marcos
    Dryer, Frederick L.
    [J]. COMBUSTION SCIENCE AND TECHNOLOGY, 2008, 180 (06) : 1053 - 1096