Ca-adsorption and apatite deposition on silk fabrics modified with phosphate polymer chains

被引:36
作者
Tamada, Y
Furuzono, T
Taguchi, T
Kishida, A
Akashi, M
机构
[1] Natl Inst Sericultural & Entomol Sci, Ibaraki, Osaka 3058634, Japan
[2] Kagoshima Univ, Fac Engn, Kagoshima 8900065, Japan
关键词
silk; hydroxyapatite; graft-copolymerization; methacryloyloxyethylphosphate;
D O I
10.1163/156856299X00649
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
Silk fabric was modified with polymethacryloyloxyethylphosphate (pMOEP) by graft copolymerization. Ca-adsorption onto pMOEP-grafted silk fabric was significantly enhanced compared to that onto original silk fabric. SEM observation indicated that some crystallites were deposited on the pMOEP-grafted silk fabric after 1 week of immersion in simulated body fluid, whereas no change occurred on the surface of the original silk fabric. X-ray diffraction showed that this crystallite contained hydroxyapatite. These results indicate that pMOEP-grafted silk fabric induce hydroxyapatite formation more effectively than the original silk fabric.
引用
收藏
页码:787 / 793
页数:7
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