Atomic scale structure and chemistry of Bi2Te3/GaAs interfaces grown by metallorganic van der Waals epitaxy

被引:26
作者
Dycus, J. Houston [1 ]
White, Ryan M. [1 ]
Pierce, Jonathan M. [2 ]
Venkatasubramanian, Rama [2 ]
LeBeau, James M. [1 ]
机构
[1] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA
[2] RTI Int, Ctr Solid State Energet, Res Triangle Pk, NC 27709 USA
关键词
THERMOELECTRIC PROPERTIES; SUPERLATTICE STRUCTURES; TOPOLOGICAL INSULATORS; VANDERWAALS EPITAXY; SB2TE3; GASE;
D O I
10.1063/1.4793518
中图分类号
O59 [应用物理学];
学科分类号
摘要
Here, we report the atomic scale structure and chemistry of epitaxial Bi2Te3 thin films grown via metallorganic chemical vapor deposition on (001) GaAs substrates. Using aberration corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF STEM), we report an atomically abrupt interface spanned by a second phase. Further, we demonstrate that interpretation of HAADF STEM image intensities does not provide an unambiguous interface structure. Combining atomic resolution imaging and spectroscopy, we determine the identity of the interfacial species is found to be consistent with that of a bilayer of Ga-Te that terminates GaAs dangling bonds. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4793518]
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页数:4
相关论文
共 26 条
[1]   Cooling, heating, generating power, and recovering waste heat with thermoelectric systems [J].
Bell, Lon E. .
SCIENCE, 2008, 321 (5895) :1457-1461
[2]   Topological insulator Bi2Te3 films synthesized by metal organic chemical vapor deposition [J].
Cao, Helin ;
Venkatasubramanian, Rama ;
Liu, Chang ;
Pierce, Jonathan ;
Yang, Haoran ;
Hasan, M. Zahid ;
Wu, Yue ;
Chen, Yong P. .
APPLIED PHYSICS LETTERS, 2012, 101 (16)
[3]   PASSIVATION OF GAAS(001) SURFACES BY INCORPORATION OF GROUP-VI ATOMS - A STRUCTURAL INVESTIGATION [J].
CHAMBERS, SA ;
SUNDARAM, VS .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1991, 9 (04) :2256-2262
[4]   Experimental Realization of a Three-Dimensional Topological Insulator, Bi2Te3 [J].
Chen, Y. L. ;
Analytis, J. G. ;
Chu, J. -H. ;
Liu, Z. K. ;
Mo, S. -K. ;
Qi, X. L. ;
Zhang, H. J. ;
Lu, D. H. ;
Dai, X. ;
Fang, Z. ;
Zhang, S. C. ;
Fisher, I. R. ;
Hussain, Z. ;
Shen, Z. -X. .
SCIENCE, 2009, 325 (5937) :178-181
[5]  
Chowdhury I, 2009, NAT NANOTECHNOL, V4, P235, DOI [10.1038/nnano.2008.417, 10.1038/NNANO.2008.417]
[6]   Preparation and thermoelectric properties of p-type (Ga2Te3)x-(Bi0.5Sb1.5Te3)1-x (x=0-0.2) alloys prepared by spark plasma sintering [J].
Cui, J. L. ;
Xue, H. F. ;
Xiu, W. J. .
INTERMETALLICS, 2007, 15 (11) :1466-1470
[7]   THE STRUCTURE OF GA2TE3 - AN X-RAY AND HIGH-RESOLUTION ELECTRON-MICROSCOPY STUDY [J].
GUYMONT, M ;
TOMAS, A ;
GUITTARD, M .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1992, 66 (01) :133-139
[8]   Epitaxy of layered compounds: GaSe on Si(111) [J].
Jedrecy, N ;
Pinchaux, R ;
Eddrief, M .
PHYSICAL REVIEW B, 1997, 56 (15) :9583-9588
[9]   Condensed matter - An insulator with a twist [J].
Kane, Charles L. .
NATURE PHYSICS, 2008, 4 (05) :348-349
[10]   Structure of the InAlAs/InP interface by atomically resolved energy dispersive spectroscopy [J].
Klenov, Dmitri O. ;
Zide, Joshua M. O. .
APPLIED PHYSICS LETTERS, 2011, 99 (14)