Daily, seasonal and monthly variations in ozone levels recorded at the Turia river basin in Valencia (Eastern Spain)

The Turia river basin, located in the east of the Iberian Peninsula, drains into the Mediterranean Sea near the city of Valencia (population, 814,208). The predominance of sea-breeze fluxes favours the inland transport of pollutants from the city up the basin where ozone concentrations exceeding the threshold for protection of human health are systematically recorded during the summer months. This work analyses the variability in ozone levels by examining their spatial and temporal distribution in a Mediterranean river basin downwind from a city within the period 2005-2008. Orographic determinants and atmospheric fluxes induce strong variations in ozone measurements, even on relatively close locations. Results show a different behaviour of the monthly means and the daily cycles depending on the season of the year and the measuring environment, with summer/winter ratios ranging from 2.4 in cities to 1.6 inland, and mean values always higher in the interior of the basin. Daily cycles show significant summer/winter differences related to the predominant situations of anticyclonic stability in winter, which limit ventilation, and the predominant breeze circulations in summer. Results also show a "weekend effect" at urban and medium-distance stations. At the most inland station, the weekend/weekday behaviour differs according to the season of the year; weekend ozone levels are higher in spring, autumn and winter, and lower in summer, coinciding with the predominance of local wind cycles that favour air mass penetration inland from the coast.