Simple Method to Determine Electronic and Ionic Components of the Conductivity in Mixed Conductors A Review

被引:335
作者
Huggins, R. A. [1 ]
机构
[1] Univ Kiel, Fac Engn, D-24143 Kiel, Germany
关键词
Perovskite; Impedance Spectroscopy; Electronic Conduction; Open Circuit; Solid Electrolyte;
D O I
10.1007/BF02376083
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In materials that are of interest for use as solid electrolytes it is important that charge transport is predominantly related to ionic motion, with minimal minority electronic conduction. On the other hand, a number of materials are mixed ionic and electronic conductors. Several DC methods that have been developed over many years to evaluate the separate electronic and ionic components of the total charge transport in solids. These include the Tubandt DC method, the DC assymetric polarization technique sometimes called the Hebb-Wagner method, and the DC open circuit potential method. This paper presents a new method that is relatively simple, and could be advantageous in some cases. It involves the employment and proper interpretation of low amplitude variable frequency AC measurements, a general technique that is often called impedance spectroscopy. As an example, the results of the use of this method on a mixed-conducting perovskite related to the well-known LSGM, La(0.4)Pr(0.4)Sr(0.2)In(0.8)Mg(0.2)O(2.8), are shown.
引用
收藏
页码:300 / 313
页数:14
相关论文
共 15 条
[1]   TRANSITION FROM SUPERCAPACITOR TO BATTERY BEHAVIOR IN ELECTROCHEMICAL ENERGY-STORAGE [J].
CONWAY, BE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (06) :1539-1548
[2]   AN ANALYSIS OF THE ASYMMETRIC POLARIZATION METHOD UNDER CONDITIONS OF RELATIVELY HIGH APPLIED VOLTAGE [J].
CROUCHBAKER, S .
SOLID STATE IONICS, 1991, 45 (1-2) :101-107
[3]  
Hittorf W., 1859, ANN PHYS-NEW YORK, V106, P543
[4]   APPLICATION OF AC TECHNIQUES TO THE STUDY OF LITHIUM DIFFUSION IN TUNGSTEN TRIOXIDE THIN-FILMS [J].
HO, C ;
RAISTRICK, ID ;
HUGGINS, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (02) :343-350
[5]   General Equivalent Circuit of Batteries and Fuel Cells [J].
Huggins, R. A. .
IONICS, 1999, 5 (3-4) :269-274
[6]   Use of defect equilibrium diagrams to understand minority species transport in solid electrolytes [J].
Huggins, RA .
SOLID STATE IONICS, 2001, 143 (01) :3-16
[8]   MIXED CONDUCTION IN ZR0.85 CA0.15 O1.85 AND TH0.85 Y0.15 O1.925 SOLID ELECTROLYTES [J].
PATTERSON, JW ;
BOGREN, EC ;
RAPP, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1967, 114 (07) :752-+
[9]   IONIC-CONDUCTIVITY OF SOME LITHIUM SILICATES AND ALUMINOSILICATES [J].
RAISTRICK, ID ;
HO, C ;
HUGGINS, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (10) :1469-1476
[10]  
RAISTRICK ID, 1977, J ELECTROANAL CHEM, V77, P319, DOI 10.1016/S0022-0728(77)80278-7