Alloying behavior and thermal stability of mechanically alloyed nano AlCoCrFeNiTi high-entropy alloy

被引:37
作者
Shivam, Vikas [1 ]
Shadangi, Yagnesh [1 ]
Basu, Joysurya [1 ]
Mukhopadhyay, Nilay Krishna [1 ]
机构
[1] Indian Inst Technol BHU, Dept Met Engn, Varanasi 221005, Uttar Pradesh, India
关键词
mechanical alloying; high-entropy alloys; thermal stability; microwave sintering; B2; phase; SOLID-SOLUTION; ANNEALING TREATMENT; SINTERING METHOD; PHASE EVOLUTION; MICROSTRUCTURE; FUNDAMENTALS; ELEMENTS; TI;
D O I
10.1557/jmr.2019.5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this investigation, we have reported the alloying behavior, phase evolution, and thermal stability of equiatomic AlCoCrFeNiTi high-entropy alloy (HEA). The 40 h milled powder shows good chemical homogeneity with agglomerated particles varying in the range of similar to 3-18 mu m. The formation of a nanostructured single-phase BCC (a = 2.85 +/- 0.01 angstrom) was observed along with the minor tungsten carbide (WC) phase that formed due to contamination during milling. Thermal stability of the alloy has been studied using dynamic differential scanning calorimetry (DSC) thermogram and in situ X-ray diffraction. It has been found that this HEA is stable up to 600 degrees C (873 K). Consolidated samples at 1000 degrees C (1273 K) showed the transformation of body centered cubic (BCC) phase into the B2 (a = 2.87 +/- 0.03 angstrom) phase co-existing with minor hexagonal WC (a = 2.90 angstrom, c = 2.83 angstrom) phase.
引用
收藏
页码:787 / 795
页数:9
相关论文
共 35 条
[1]   Glass forming ability: Miedema approach to (Zr, Ti, Hf)-(Cu, Ni) binary and ternary alloys [J].
Basu, Joysurya ;
Murty, B. S. ;
Ranganathan, S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 465 (1-2) :163-172
[2]   Microstructural development in equiatomic multicomponent alloys [J].
Cantor, B ;
Chang, ITH ;
Knight, P ;
Vincent, AJB .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 375 :213-218
[3]   Alloying behavior, microstructure and mechanical properties in a FeNiCrCo0.3Al0.7 high entropy alloy [J].
Chen, Weiping ;
Fu, Zhiqiang ;
Fang, Sicong ;
Xiao, Huaqiang ;
Zhu, Dezhi .
MATERIALS & DESIGN, 2013, 51 :854-860
[4]   Competition between elements during mechanical alloying in an octonary multi-principal-element alloy system [J].
Chen, Yu-Liang ;
Hu, Ya-Huei ;
Hsieh, Cheng-An ;
Yeh, Jien-Wei ;
Chen, Swe-Kai .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 481 (1-2) :768-775
[5]   The effect of molybdenum on the corrosion behaviour of the high-entropy alloys Co1.5CrFeNi1.5Ti0.5Mox in aqueous environments [J].
Chou, Y. L. ;
Yeh, J. W. ;
Shih, H. C. .
CORROSION SCIENCE, 2010, 52 (08) :2571-2581
[6]   Influence of Cr removal on the microstructure and mechanical behaviour of a high-entropy Al0.8Ti0.2CoNiFeCr alloy fabricated by powder metallurgy [J].
Fu, Zhiqiang ;
Chen, Weiping ;
Jiang, Zhenfei ;
MacDonald, Benjamin E. ;
Lin, Yaojun ;
Chen, Fei ;
Zhang, Lianmeng ;
Lavernia, Enrique J. .
POWDER METALLURGY, 2018, 61 (02) :106-114
[7]   Microstructure and strengthening mechanisms in an FCC structured single-phase nanocrystalline Co25Ni25Fe25Al7.5Cu17.5 high-entropy alloy [J].
Fu, Zhiqiang ;
Chen, Weiping ;
Wen, Haiming ;
Zhang, Dalong ;
Chen, Zhen ;
Zheng, Baolong ;
Zhou, Yizhang ;
Lavernia, Enrique J. .
ACTA MATERIALIA, 2016, 107 :59-71
[8]   Effects of Co and sintering method on microstructure and mechanical behavior of a high-entropy Al0.6NiFeCrCo alloy prepared by powder metallurgy [J].
Fu, Zhiqiang ;
Chen, Weiping ;
Wen, Haiming ;
Chen, Zhen ;
Lavernia, Enrique J. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 646 :175-182
[9]   Influence of Ti addition and sintering method on microstructure and mechanical behavior of a medium-entropy Al0.6CoNiFe alloy [J].
Fu, Zhiqiang ;
Chen, Weiping ;
Chen, Zhen ;
Wen, Haiming ;
Lavernia, Enrique J. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2014, 619 :137-145
[10]   Structure and properties of ultrafine-grained CoCrFeMnNi high-entropy alloys produced by mechanical alloying and spark plasma sintering [J].
Joo, S. -H. ;
Kato, H. ;
Jang, M. J. ;
Moon, J. ;
Kim, E. B. ;
Hong, S. -J. ;
Kim, H. S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 698 :591-604