Broadband dielectric spectroscopy of CuInP2Se6 crystals

被引:12
作者
Macutkevic, Jan [1 ]
Banys, Juras [2 ]
Vysochanskii, Yulian [3 ]
机构
[1] Lithuania Acad Sci, Inst Semicond Phys, LT-2600 Vilnius, Lithuania
[2] Vilnius State Univ, Fac Phys, LT-10222 Vilnius, Lithuania
[3] Uzhgorod State Univ, Inst Solid State Phys & Chem, UA-88000 Uzhgorod, Ukraine
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2009年 / 206卷 / 01期
关键词
PHASE-TRANSITION;
D O I
10.1002/pssa.200824231
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Investigation results of broadband dielectric (from 20 Hz to 1.2 GHz) properties of layered CuInP2Se6 crystals are presented. The temperature dependence of the static dielectric permittivity reveals a ferroelectric phase transition at T-c = 225 K. In the paraelectric phase, at low frequencies, dielectric spectra are highly influenced by the high ionic conductivity with the activation energy of 3653.4 K (0.315 eV). In, the ferroelectric phase the electrical conductivity and its activation energy (531.1 K (0.045 eV)) are considerably smaller. The high-frequency part of the spectra is determined by a relaxational soft mode. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:167 / 172
页数:6
相关论文
共 17 条
[1]   THE DETERMINATION OF HOPPING RATES AND CARRIER CONCENTRATIONS IN IONIC CONDUCTORS BY A NEW ANALYSIS OF AC CONDUCTIVITY [J].
ALMOND, DP ;
DUNCAN, GK ;
WEST, AR .
SOLID STATE IONICS, 1983, 8 (02) :159-164
[2]   Dipolar glass behaviour in mixed CuInP2(S0.7Se0.3)6 crystals [J].
Banys, J ;
Grigalaitis, R ;
Macutkevic, J ;
Brilingas, A ;
Samulionis, V ;
Grigas, J ;
Vysochanskii, Y .
FERROELECTRICS, 2005, 318 :163-168
[3]   Dielectric and ultrasonic investigation of phase transition in CuInP2S6 crystals [J].
Banys, J ;
Macutkevic, J ;
Samulionis, V ;
Brilingas, A ;
Vysochanskii, Y .
PHASE TRANSITIONS, 2004, 77 (04) :345-358
[4]   Dielectric properties in the vicinity of phase transition of new ferroelectric CuInP2S6 [J].
Banys, J ;
Samulionis, V ;
Cajipe, V .
FERROELECTRICS, 1999, 223 (1-4) :43-50
[5]   Crossover Between Ferroelectric Order and Dipolar Glass Disorder in CuInP2(S0.25Se0.75)6 Crystals [J].
Banys, J. ;
Macutkevic, J. ;
Samulionis, V. ;
Brilingas, A. ;
Sobiestijanskas, R. ;
Vysochanskii, Yu .
FERROELECTRICS, 2007, 346 :136-142
[6]   Copper sublattice ordering in layered CuMP2Se6 (M=In, Cr) [J].
Bourdon, X ;
Maisonneuve, V ;
Cajipe, VB ;
Payen, C ;
Fischer, JE .
JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 283 (1-2) :122-127
[7]   Interplay between electronic and crystallographic instabilities in the low-dimensional ferroelectric CuInP2Se6 [J].
Fagot-Revurat, Y ;
Bourdon, X ;
Bertran, F ;
Cajipe, VB ;
Malterre, D .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (03) :595-602
[8]  
Grigas J., 1996, MICROWAVE DIELECTRIC, P335
[9]   Asymmetric phase diagram of mixed CuInP2(SxSe1-x)6 crystals [J].
Macutkevic, J. ;
Banys, J. ;
Grigalaitis, R. ;
Vysochanskii, Yu. .
PHYSICAL REVIEW B, 2008, 78 (06)
[10]   Ferrielectric ordering in lamellar CuInP2S6 [J].
Maisonneuve, V ;
Cajipe, VB ;
Simon, A ;
VonDerMuhll, R ;
Ravez, J .
PHYSICAL REVIEW B, 1997, 56 (17) :10860-10868