A new modulated structure in α-Fe2O3 nanowires

被引:1
作者
Cai Rong-Sheng [1 ]
Shang Lei [1 ]
Liu Xue-Hua [1 ,2 ]
Wang Yi-Qian [1 ]
Yuan Lu [3 ,4 ]
Zhou Guang-Wen [3 ,4 ]
机构
[1] Qingdao Univ, State Key Lab, Cultivat Base, Qingdao 266071, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Lab Adv Mat & Electron Microscopy, Beijing 100190, Peoples R China
[3] SUNY Binghamton, Dept Mech Engn, Binghamton, NY 13902 USA
[4] SUNY Binghamton, Multidisciplinary Program Mat Sci & Engn, Binghamton, NY 13902 USA
关键词
crystal structure; nanocrystalline materials; electron microscopy; simulation and modeling; GROWTH; OXIDATION; DEFECTS;
D O I
10.1088/1674-1056/22/10/107401
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A new modulated structure consisting of periodic (11 (2) over bar0) stacking faults (SFs) in the alpha-Fe2O3 nanowires (NWs) formed by the thermal oxidation of Fe foils is reported, using a combination of high-resolution transmission electron microscopy (HRTEM) observations and HRTEM image simulations. The periodicity of the modulated structure is 1.53 nm, which is ten times (3 (3) over bar 00) interplanar spacing and can be described by a shift of every ten (3 (3) over bar 00) planes with 1/2 the interplanar spacing of the (11 (2) over bar0) plane. An atomic model for the Fe2O3 structure is proposed to simulate the modulated structure. HRTEM simulation results confirm that the modulated structure in alpha-Fe2O3 NWs is caused by SFs.
引用
收藏
页数:4
相关论文
共 22 条
[1]   Growth mechanism and photoluminescence of the SnO2 nanotwists on thin film and the SnO2 short nanowires on nanorods [J].
Bing, Wang ;
Ping, Xu .
CHINESE PHYSICS B, 2009, 18 (01) :324-332
[2]   One-dimensional steeplechase for electrons realized [J].
Björk, MT ;
Ohlsson, BJ ;
Sass, T ;
Persson, AI ;
Thelander, C ;
Magnusson, MH ;
Deppert, K ;
Wallenberg, LR ;
Samuelson, L .
NANO LETTERS, 2002, 2 (02) :87-89
[3]   Formation of modulated structures in single-crystalline hexagonal α-Fe2O3 nanowires [J].
Cai, R. S. ;
Li, T. ;
Wang, Y. Q. ;
Wang, C. ;
Yuan, L. ;
Zhou, G. W. .
JOURNAL OF NANOPARTICLE RESEARCH, 2012, 14 (08)
[4]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[5]   Systematic study of the growth of aligned arrays of α-Fe2O3 and Fe3O4 nanowires by a vapor-solid process [J].
Chueh, Yu-Lun ;
Lai, Ming-Wei ;
Liang, Jia-Qi ;
Chou, Li-Jen ;
Wang, Zhong Lin .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (17) :2243-2251
[6]   ELECTRON-ENERGY-LOSS-SPECTROSCOPY NEAR-EDGE FINE-STRUCTURES IN THE IRON-OXYGEN SYSTEM [J].
COLLIEX, C ;
MANOUBI, T ;
ORTIZ, C .
PHYSICAL REVIEW B, 1991, 44 (20) :11402-11411
[7]   Spontaneous Growth of Superstructure α-Fe2O3 Nanowire and Nanobelt Arrays in Reactive Oxygen Plasma [J].
Cvelbar, Uros ;
Chen, Zhiqiang ;
Sunkara, Mahendra K. ;
Mozetic, Miran .
SMALL, 2008, 4 (10) :1610-1614
[8]   POINT-DEFECTS AND TRANSPORT IN HEMATITE (FE2O3-EPSILON) [J].
DIECKMANN, R .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1993, 68 (04) :725-745
[9]   Monte Carlo study for the growth of α-Fe2O3 nanowires synthesized by thermal oxidation of iron [J].
Dong, Zhao ;
Kashkarov, Pavel ;
Zhang, Han .
NANOSCALE, 2010, 2 (04) :524-528
[10]   Synthesis of Fe2O3 nanowires by oxidation of iron [J].
Fu, YY ;
Chen, J ;
Zhang, H .
CHEMICAL PHYSICS LETTERS, 2001, 350 (5-6) :491-494