Rhodium(III)-Catalyzed Intermolecular N-Chelator-Directed Aromatic C-H Amidation with Amides

被引：106

作者：

Zhao, Huaiqing ^{[1
]}

Shang, Yaping ^{[1
]}

Su, Weiping ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 19期

关键词：

CATALYZED DIRECT AMINATION; CARBON-NITROGEN BONDS; ARENES; ACTIVATION; RHODIUM; FUNCTIONALIZATION; RH; VERSATILE; ALKENES; ALKYNES;

D O I：

10.1021/ol4024776

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rh(III)-catalyzed intermolecular direct aromatic C-H bond amidation with amides has been accomplished under mild reaction conditions. This protocol is applicable to a broad range of N-chelator-containing arenes amidated with aromatic and aliphatic sulfonamides. A possible mechanism is proposed according to the experimental results.

引用

页码：5106 / 5109

页数：4

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