Slip-inversion-slip mechanism of phosphametallocene isomerization.: Spectroscopic characterization of an (η1-phospholyl)titanium complex.: Synthesis and structures of chiral mono(phospholyl)titanium complexes

被引：16

作者：

Ahn, YJ ^{[1
]}

Rubio, RJ ^{[1
]}

Hollis, TK ^{[1
]}

Tham, FS ^{[1
]}

Donnadieu, B ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 05期

关键词：

D O I：

10.1021/om050357h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first reported synthesis and spectroscopic characterization of a group 4 eta(1)-phospholyl complex, (eta(1)-dibenzophospholyl)tris(dimethylamido)titanium, are documented, which has an eta(1)-phospholyl ligand analogous to those proposed in the slip-inversion-slip mechanism of phosphametallocene isomerization.

引用

页码：1079 / 1083

页数：5

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