Values of the mass transfer coefficient of the linear driving force model for VOC adsorption on activated carbons

被引:44
作者
Chauveau, Romain [1 ,2 ]
Grevillot, Georges [1 ]
Marsteau, Stephanie [2 ]
Vallieres, Cecile [1 ]
机构
[1] Univ Lorraine, CNRS, Lab React & Genie Proc, F-54001 Nancy, France
[2] INRS, Lab Filtrat & Adsorpt, F-54500 Vandoeuvre Les Nancy, France
关键词
Mass transfer; Activated carbon; Linear driving force; Volatile organic compounds; WHEELER-JONAS EQUATION; WATER-VAPOR; BREAKTHROUGH; KINETICS; PREDICTION; BED; DESORPTION; DYNAMICS; SIMULATION; CONSTANT;
D O I
10.1016/j.cherd.2012.09.019
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Modelling of activated carbon cartridges is essential in personal protective equipments against toxic gases in order to know the duration of protection. The linear driving force model seems to be more adapted than the actual Wheeler-Jonas model because it has more physical significance. The difficulty is that the mass transfer coefficient can not be calculated a priori. Values of the LDF mass transfer coefficient are disseminated in the literature and thus there is no overview of the range and variations with different adsorbents, adsorbates and concentrations. The object of this paper is thus twofold: obtaining values of the mass transfer coefficient at different concentrations and adsorbates in order to have a comprehensive view of.variations and appreciating the validity of the LDF constant pattern model. (C) 2012 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:955 / 962
页数:8
相关论文
共 47 条
[1]   Effects of capillary condensation on adsorption and thermal desorption dynamics of water in zeolite 13X and layered beds [J].
Ahn, H ;
Lee, CH .
CHEMICAL ENGINEERING SCIENCE, 2004, 59 (13) :2727-2743
[2]   Pressure effects in adsorption systems [J].
Arumugam, BK ;
Banks, JF ;
Wankat, PC .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 1999, 5 (03) :261-278
[3]   Mass transfer in VOC adsorption on zeolite: Experimental and theoretical breakthrough curves [J].
Brosillon, S ;
Manero, MH ;
Foussard, JN .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (17) :3571-3575
[4]   Prediction of breakthrough curves for adsorption on activated carbon fibers in a fixed bed [J].
Cheng, TB ;
Jiang, Y ;
Zhang, YP ;
Liu, SQ .
CARBON, 2004, 42 (15) :3081-3085
[5]   Transport and sorption of water vapour in activated carbons [J].
Cossarutto, L ;
Zimny, T ;
Kaczmarczyk, J ;
Siemieniewska, T ;
Bimer, J ;
Weber, JV .
CARBON, 2001, 39 (15) :2339-2346
[6]   Mass transfer and warming during adsorption of high concentrations of VOCs on an activated carbon bed:: Experimental and theoretical analysis [J].
Delage, F ;
Pré, P ;
Le Cloirec, P .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (22) :4816-4821
[7]   On the surface diffusion of hydrocarbons in microporous activated carbon [J].
Do, HD ;
Do, DD ;
Prasetyo, I .
CHEMICAL ENGINEERING SCIENCE, 2001, 56 (14) :4351-4368
[8]  
DUBININ MM, 1947, ZH FIZ KHIM+, V21, P1351
[9]  
DUBININ MM, 1949, ZH FIZ KHIM+, V23, P1129
[10]   Adsorption and desorption kinetics for hydrophilic and hydrophobic vapors on activated carbon [J].
Fletcher, AJ ;
Yüzak, Y ;
Thomas, KM .
CARBON, 2006, 44 (05) :989-1004