Reduced Graphene Oxide Mediated SnO2 Nanocrystals for Enhanced Gas-sensing Properties

被引:76
作者
Chang, Yanhong [1 ]
Yao, Yunfeng [1 ,2 ]
Wang, Bin [2 ]
Luo, Hui [3 ]
Lie, Tianyi [1 ]
Zhi, Linjie [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Civil & Environm Engn, Beijing 100083, Peoples R China
[2] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[3] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China
关键词
SnO2-rGO; Gas sensor; Sensitivity; Response-recovery time; SENSOR; NANOCOMPOSITES; NANOTUBES; MOLECULES; ROUTE; NO2; CO;
D O I
10.1016/j.jmst.2012.11.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
SnO2 reduced graphene oxide (SnO2-rGO) composites were prepared via a hydro thermal reaction of graphene oxide (GO) and SnC1(2).2H(2)O in the mixed solvent of ethylene glycol and water. During the redox reaction, GO was reduced to rGO while Sn2+ was oxidized to SnO2, uniformly depositing on the surface of rGO sheets. The composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), infrared spectra analysis (IR) and transmission electron microscopy (TEM), respectively, and their gas sensing properties were further investigated. Compared with pure SnO2 nanoparticles, the as-prepared SnO2-rGO gas sensor showed much better gas sensing behavior in sensitivity and response recovery time to ethanol and H2S at low concentrations. Overall, the highly sensitive, quick-responding and low cost SnO2-rGO gas sensor could be potentially applied in environmental monitoring area.
引用
收藏
页码:157 / 160
页数:4
相关论文
共 28 条
[1]   Graphene/Polyaniline Nanocomposite for Hydrogen Sensing [J].
Al-Mashat, Laith ;
Shin, Koo ;
Kalantar-zadeh, Kourosh ;
Plessis, Johan D. ;
Han, Seung H. ;
Kojima, Robert W. ;
Kaner, Richard B. ;
Li, Dan ;
Gou, Xinglong ;
Ippolito, Samuel J. ;
Wlodarski, Wojtek .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (39) :16168-16173
[2]   WO3 nanorods/graphene nanocomposites for high-efficiency visible-light-driven photocatalysis and NO2 gas sensing [J].
An, Xiaoqiang ;
Yu, Jimmy C. ;
Wang, Yu ;
Hu, Yongming ;
Yu, Xuelian ;
Zhang, Guangjin .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (17) :8525-8531
[3]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[4]   Highly sensitive CO and ethanol nanoflower-like SnO2 sensor among various morphologies obtained by using single and mixed ionic surfactant templates [J].
Firooz, Azam Anaraki ;
Mahjoub, Ali Reza ;
Khodadadi, Abbas Ali .
SENSORS AND ACTUATORS B-CHEMICAL, 2009, 141 (01) :89-96
[5]   A chemical route to graphene for device applications [J].
Gilje, Scott ;
Han, Song ;
Wang, Minsheng ;
Wang, Kang L. ;
Kaner, Richard B. .
NANO LETTERS, 2007, 7 (11) :3394-3398
[6]   Adsorption of gas molecules on graphene nanoribbons and its implication for nanoscale molecule sensor [J].
Huang, Bing ;
Li, Zuanyi ;
Liu, Zhirong ;
Zhou, Gang ;
Hao, Shaogang ;
Wu, Jian ;
Gu, Bing-Lin ;
Duan, Wenhui .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (35) :13442-13446
[7]   Graphene Films and Ribbons for Sensing of O2, and 100 ppm of CO and NO2 in Practical Conditions [J].
Joshi, Rakes K. ;
Gomez, Humberto ;
Alvi, Farah ;
Kumar, Ashok .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (14) :6610-6613
[8]   Highly sensitive and ultra-fast responding gas sensors using self-assembled hierarchical SnO2 spheres [J].
Kim, Hae-Ryong ;
Choi, Kwon-Il ;
Lee, Jong-Heun ;
Akbar, Sheikh A. .
SENSORS AND ACTUATORS B-CHEMICAL, 2009, 136 (01) :138-143
[9]   Room Temperature Ionic Liquids Assisted Green Synthesis of Nanocrystalline Porous SnO2 and Their Gas Sensor Behaviors [J].
Li, Le-Le ;
Zhang, Wei-Ming ;
Yuan, Quan ;
Li, Zhen-Xing ;
Fang, Cheng-Jie ;
Sun, Ling-Dong ;
Wan, Li-Jun ;
Yan, Chun-Hua .
CRYSTAL GROWTH & DESIGN, 2008, 8 (11) :4165-4172
[10]   Preparation of SnO2-Nanocrystal/Graphene-Nanosheets Composites and Their Lithium Storage Ability [J].
Li, Yueming ;
Lv, Xiaojun ;
Lu, Jin ;
Li, Jinghong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (49) :21770-21774