Nickel-Catalyzed Suzuki-Miyaura Coupling of Heteroaryl Ethers with Arylboronic Acids

被引：57

作者：

Li, Xiao-Jian

Zhang, Jin-Ling

Geng, Yu

Jin, Zhong ^{[1
]}

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 10期

基金：

中国国家自然科学基金;

关键词：

ARYL CARBON-OXYGEN; ORGANOBORON COMPOUNDS; ANILINE DERIVATIVES; BOND FORMATION; BORONIC ACIDS; ACTIVATION; ESTERS; 2-CHLORO-4,6-DIMETHOXY-1,3,5-TRIAZINE; ELECTROPHILES; CONSTRUCTION;

D O I：

10.1021/jo4005537

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nickel-catalyzed Suzuki-Miyaura coupling of heteroaryl ethers with arylboronic acids was described. Selective activation of the phenol C-O bonds was achieved by converting them into the corresponding aryl 2,4-dimethoxy-1,3,5-triazine-6-yl ethers, in which aryl C-O bond could be selectively cleaved with inexpensive, air-stable NiCl2(dppf) as a catalyst. Coupling of these readily accessible heteroaryl ethers proved tolerant of extensive functional groups.

引用

页码：5078 / 5084

页数：7

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