Mass and microwave spectroscopic studies of the pyrolysis of oxime compounds .2.

被引：3

作者：

Sakaizumi, T

Morii, H

Murakami, K

Ohashi, O

机构：

[1] Department of Chemistry, Faculty of Science and Technology, Sophia University, Tokyo 102, Kioi-cho, Chiyoda-ku

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1996年 / 36卷 / 01期

关键词：

acetonitrile; acetonitrile-N-oxide; formaldehyde; mass spectrometry; microwave spectroscopy; pyrolysis; pyrolysis mechanism;

D O I：

10.1016/0165-2370(95)00923-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The pyrolysates of three oximes (XCH(2)C(CH3)=NOH, X = H, CH3, Cl) have been investigated by pyrolysis-mass spectrometry/microwave spectroscopy (Py-MS/MW). The pyrolysis mechanisms of XCH(2)C(CH3)=NOH (X = H and CH3) were different from those of XCH(2)CH=NOH reported previously. Although the observed pyrolysates were different for the different substituent groups (X), acetonitrile was observed from all the precursors.

引用

页码：99 / 102

页数：4

共 7 条

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