Synthesis and structures of poly (perfluoroethyl)[60]fullerenes:: 1,7,16,36,46,49-C60(C2F5)6 and 1,6,11,18,24,27,32,35-C60(C2F5)8

被引:34
作者
Kareev, IE
Kuvychko, IV
Lebedkin, SF
Miller, SM
Anderson, OP
Strauss, SH [1 ]
Boltalina, OV
机构
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Russia
[3] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany
关键词
D O I
10.1039/b513477c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The high-temperature reaction of C-60 and C2F5I produced poly(perfluoroethyl)fullerenes with unprecedented addition patterns.
引用
收藏
页码:308 / 310
页数:3
相关论文
共 15 条
[1]   Fluorine-fluorine spin-spin coupling constants in aromatic compounds: Correlations with the delocalization index and with the internuclear separation [J].
Castillo, N ;
Matta, CF ;
Boyd, RJ .
JOURNAL OF CHEMICAL INFORMATION AND MODELING, 2005, 45 (02) :354-359
[2]   Novel addition in trifluoromethylation of [70]fullerene [J].
Darwish, AD ;
Abdul-Sada, AK ;
Avent, AG ;
Martsinovich, N ;
Street, JM ;
Taylor, R .
JOURNAL OF FLUORINE CHEMISTRY, 2004, 125 (09) :1383-1391
[3]   Unusual addition patterns in trifluoromethylation of [60]fullerene [J].
Darwish, AD ;
Abdul-Sada, AK ;
Avent, AG ;
Lyakhovetsky, Y ;
Shilova, EA ;
Taylor, R .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (17) :3102-3110
[4]   PRODUCTION OF PERFLUOROALKYLATED NANOSPHERES FROM BUCKMINSTERFULLERENE [J].
FAGAN, PJ ;
KRUSIC, PJ ;
MCEWEN, CN ;
LAZAR, J ;
PARKER, DH ;
HERRON, N ;
WASSERMAN, E .
SCIENCE, 1993, 262 (5132) :404-407
[5]  
Gakh YG, 2000, MAGN RESON CHEM, V38, P551, DOI 10.1002/1097-458X(200007)38:7<551::AID-MRC686>3.0.CO
[6]  
2-Q
[7]   Trifluoromethylated [60]fullerenes: Synthesis and characterization [J].
Goryunkov, AA ;
Ioffe, IN ;
Kuvychko, IV ;
Yankova, TS ;
Markov, VY ;
Streletskii, AA ;
Dick, DL ;
Sidorov, LN ;
Boltalina, OV ;
Strauss, SH .
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2004, 12 (1-2) :181-185
[8]   Isolation of C60(CF3)n (n=2, 4, 6, 8, 10) with high compositional purity [J].
Goryunkov, AA ;
Kuvychko, IV ;
Ioffe, IN ;
Dick, DL ;
Sidorov, LN ;
Strauss, SH ;
Boltalina, OV .
JOURNAL OF FLUORINE CHEMISTRY, 2003, 124 (01) :61-64
[9]   Trifluoromethylated endohedral metallofullerenes:: Synthesis and characterization of Y@C82(CF3)5 [J].
Kareev, IE ;
Lebedkin, SF ;
Bubnov, VP ;
Yagubskii, EB ;
Ioffe, IN ;
Khavrel, PA ;
Kuvychko, IV ;
Strauss, SH ;
Boltalina, OV .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (12) :1846-1849
[10]   Variable-temperature 19F NMR and theoretical study of 1,9- and 1,7-C60F(CF3) and Cs- and C1-C60F17(CF3):: Hindered CF3 rotation and through-space JFF coupling [J].
Kareev, IE ;
Quiñones, GS ;
Kuvychko, IV ;
Khavrel, PA ;
Ioffe, IN ;
Goldt, IV ;
Lebedkin, SF ;
Seppelt, K ;
Strauss, SH ;
Boltalina, OV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (32) :11497-11504