Synthesis and electrochemical properties of peripheral, non-peripheral tetra [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] substituted cobalt(II), manganese(III) phthalocyanines

被引:9
作者
Keles, Turgut [1 ]
Biyiklioglu, Zekeriya [1 ]
Gultekin, Ergun [1 ]
Bekircan, Olcay [1 ]
机构
[1] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
关键词
Synthesis; Phthalocyanine; 1,2,4-Triazol; Electrochemistry; MICROWAVE-ASSISTED SYNTHESIS; SPECTROELECTROCHEMICAL PROPERTIES; METAL-FREE; METALLOPHTHALOCYANINES; ZINC(II); ELECTROPOLYMERIZATION; COPPER(II); MOIETIES; THERAPY;
D O I
10.1016/j.ica.2018.12.010
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN, 3-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile n-ET-CN and cobalt(II), manganese(III) phthalocyanines bearing [2(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were synthesized for the first time. The new compounds have been characterized by FT-IR, NMR (only for ET-CN, n-ET-CN), mass and UV-Vis spectroscopy (except ET-CN, n-ET-CN) techniques. Electrochemistry of cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were examined by using cyclic voltammetry.
引用
收藏
页码:201 / 207
页数:7
相关论文
共 50 条
[41]   Crystal structure of 2-(2-methyl-5-(6-(1-methyl-5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl)pyridin-2-yl)-2H-1,2,4-triazol-3-yl)pyrazine manganese(II) dibromide, C19H15Br2MnN11 [J].
Wei, Xue-Feng ;
Miao, Juan ;
Shi, Ling-Ling .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2015, 230 (02) :123-124
[42]   Electropolymerizable peripherally tetra-{2-[3-(diethylamino) phenoxy]ethoxy} substituted as well as axially (4-phenylpiperazin-1-yl)-propanoxy-disubstituted silicon phthalocyanines and their electrochemistry [J].
Biyiklioglu, Zekeriya ;
Alp, Hakan .
DALTON TRANSACTIONS, 2015, 44 (43) :18993-18999
[43]   Synthesis and study of complexes of cobalt(II), nickel(II), and copper(II) halides with 2-(3,5-dimethylpyrazol-1-yl)benzimidazole [J].
Ivanova, A. D. ;
Kuz'menko, T. A. ;
Komarov, V. Yu. ;
Glinskaya, L. A. ;
Sheludyakova, L. A. ;
Klyushova, L. S. ;
Lavrenova, L. G. .
RUSSIAN CHEMICAL BULLETIN, 2021, 70 (08) :1550-1559
[44]   Synthesis and study of complexes of cobalt(II), nickel(II), and copper(II) halides with 2-(3,5-dimethylpyrazol-1-yl)benzimidazole [J].
A. D. Ivanova ;
T. A. Kuz’menko ;
V. Yu. Komarov ;
L. A. Glinskaya ;
L. A. Sheludyakova ;
L. S. Klyushova ;
L. G. Lavrenova .
Russian Chemical Bulletin, 2021, 70 :1550-1559
[45]   Synthesis and crystal structure of 5-[(1H-1,2,4-triazol-1-yl)methyl]-4-(2,3-dimethoxybenzylideneamino)-2-2H-1,2,4-triazole-3(4H)-thione monohydrate [J].
Xu Liang-Zhong ;
Shang Yu-Qing ;
Yu Guan-Ping ;
Li Kai ;
Si Guo-Dong .
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (06) :673-676
[46]   Synthesis, Crystal Structure and Antitumor Activity of (E)-1-(7-Methoxy-2,2-dimethyl-2,3-dihydrobenzofuran-5-yl)-3-(2-methoxyphenyl)-2-(1H-1,2,4-triazol-1-yl)propenol [J].
Li Shui-Shi ;
Li Wan ;
Ye Jiao ;
Hu Ai-Xi .
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36 (07) :1142-1146
[47]   Synthesis,Crystal Structure and Antitumor Activity of (E)-1-(7-Methoxy-2,2-dimethyl-2,3-dihydrobenzofuran-5-yl)-3-(2-methoxyphenyl)-2-(1H-1,2,4-triazol-1-yl)propenol [J].
李水师 ;
李婉 ;
叶姣 ;
胡艾希 .
结构化学, 2017, 36 (07) :1142-1146
[48]   Synthesis and Biological Activity of N-Substituted Benzylidene-4-(4-methoxyphenyl)-5-(1H-1,2,4-triazol-1-yl)-1,3-thiazol-2-amine [J].
Dai, Hong ;
Zhou, Xin ;
Shao, Ling ;
Liu, Jianbing ;
Qin, Xue ;
Fang, Jianxin .
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 32 (09) :1715-1718
[49]   Synthesis, characterization, and investigation of photochemical properties of tetra-substituted zinc phthalocyanines bearing 4-(3,5-dimethyl-1H-pyrazol-1-yl)phenyl moiety with different linker heteroatoms [J].
Ziminov, Andrey, V ;
Sidunets, Yuri A. ;
Fundamensky, Vladimir S. ;
Gurzhiy, Vladislav V. ;
Ramsh, Stanislav M. .
INORGANICA CHIMICA ACTA, 2020, 501
[50]   Structure-activity relationships of 3-methyl and 3,3-dimethyl analogs of 2-(2,4-difluorophenyl)-3-(omega-substituted alkyl)sulfonyl-1-(1H-1,2,4-triazol-1-yl)-2-propanols [J].
Miyauchi, H ;
Kozuki, K ;
Tanio, T ;
Ohashi, N .
CHEMICAL & PHARMACEUTICAL BULLETIN, 1996, 44 (04) :785-792