Synthesis and electrochemical properties of peripheral, non-peripheral tetra [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] substituted cobalt(II), manganese(III) phthalocyanines

被引：9
作者：
Keles, Turgut [1 ]
Biyiklioglu, Zekeriya [1 ]
Gultekin, Ergun [1 ]
Bekircan, Olcay [1 ]
机构：
[1] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
来源：
INORGANICA CHIMICA ACTA | 2019年 / 487卷
关键词：
Synthesis; Phthalocyanine; 1,2,4-Triazol; Electrochemistry; MICROWAVE-ASSISTED SYNTHESIS; SPECTROELECTROCHEMICAL PROPERTIES; METAL-FREE; METALLOPHTHALOCYANINES; ZINC(II); ELECTROPOLYMERIZATION; COPPER(II); MOIETIES; THERAPY;
D O I：
10.1016/j.ica.2018.12.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN, 3-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile n-ET-CN and cobalt(II), manganese(III) phthalocyanines bearing [2(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were synthesized for the first time. The new compounds have been characterized by FT-IR, NMR (only for ET-CN, n-ET-CN), mass and UV-Vis spectroscopy (except ET-CN, n-ET-CN) techniques. Electrochemistry of cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were examined by using cyclic voltammetry.
引用
收藏
页码：201 / 207
页数：7
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