A Fluorescence Turn-on Sensor for Cyanide Anion Based on Exciplex Signaling Mechanism

被引：11
作者：
Zhou, Xianshu [1 ]
Yang, Hengquan [2 ]
Hao, Junsheng [2 ]
Yin, Caixia [3 ]
Liu, Diansheng [1 ]
Guo, Wei [2 ]
机构：
[1] Shanxi Univ, RIAC, Taiyuan 030006, Peoples R China
[2] Shanxi Univ, Coll Chem & Chem Engn, Dept Chem, Taiyuan 030006, Peoples R China
[3] Shanxi Univ, IMS, Minist Educ, Key Lab Chem Biol & Mol Engn, Taiyuan 030006, Peoples R China
来源：
CHEMISTRY LETTERS | 2012年 / 41卷 / 05期
关键词：
ION-PAIR RECOGNITION; SELECTIVE DETECTION; AQUEOUS-SOLUTION; SODIUM-CYANIDE; WATER; PROBE; CHEMOSENSOR; CHEMODOSIMETER; SPIROPYRAN; EMISSION;
D O I：
10.1246/cl.2012.518
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new fluorescent chemosensor comprising anthracene and indanedione-based Michael receptor, which recognizes cyanide anion with high selectivity was designed and synthesized. The Michael addition of cyanide to the chemosensor elicits a fluorescence enhancement at a longer wavelength, which constituted the signature for cyanide detection. The mechanism of exciplex formation was proposed for the interesting observation.
引用
收藏
页码：518 / 520
页数：3
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