Organobismuth(III) and Dibismuthine Complexes Bearing N,N′-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity

被引：17

作者：

Nekoueishahraki, Lijan ^{[1
]}

Samuel, Prinson P. ^{[1
]}

Roesky, Herbert W. ^{[1
]}

Stern, Daniel ^{[1
]}

Matussek, Julia ^{[1
]}

Stalke, Dietmar ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 18期

关键词：

CRYSTAL-STRUCTURE; BISMUTH; DERIVATIVES; TETRAMESITYLDIBISMUTHANE; HALIDES;

D O I：

10.1021/om300758s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organobismuth(III) and dibismuthine complexes bearing N,N'-disubstituted 1,8-diaminonaphthalene ligand were prepared. The reaction of LBiNMe2 (1) [L = 1,8-(NSiMe3)(2)C10H6] with ClSiMe3 results in the elimination of Me3SiNMe2, while PhCCH, Cp*H, and PhOH proceed via HNMe2 elimination and provide the complexes of LBiCl (2), LBiCCPh (3), LBiCp*(4), and LBiOPh (5), respectively. Reaction of 1 with AlMe3 in n-hexane yields LBiMe (6). Compound 1 reacts with diisopropylcarbodiimide and phenyl isocyanate under insertion at the Bi-NMe2 bond to give the addition products LBi(NiPr)(2)CNMe2 (7) and LBiN(Ph)C(O)NMe2 (8). The reactions of 1 with sulfur and PhSiH3 result in the formation of LBi-S-BiL (9) and LBi-BiL (10), respectively. Compounds 2-10 were characterized by elemental analysis, H-1, C-13, and Si-29 NMR spectroscopy, and X-ray crystallographic studies.

引用

页码：6697 / 6703

页数：7

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