Partitioning of the quinary reciprocal system Li,KaEuro-F,Cl,Br,MoO4 into simplexes and the investigation of its partitioning and stable elements

被引：0

作者：

Garkushin, I. K. ^{[1
]}

Demina, M. A. ^{[1
]}

Bekhtereva, E. M. ^{[1
]}

机构：

[1] Samara State Tech Univ, Samara, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 59卷 / 03期

关键词：

LiCl; Salt System; Stable Element; Polythermal Section; Binary Side;

D O I：

10.1134/S003602361403005X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The quinary reciprocal system Li,KaEuro-F,Cl,Br,MoO4 was partitioned into simplexes using graph theory. A tree of phases of the system was constructed, and stable elements were identified. The chemical interaction in the system Li,KaEuro-F,Cl,Br,MoO4 was described by the ion balance method. The stable tetrahedra LiF-KCl-KBr-K2MoO4, LiF-KCl-KBr-LiKMoO4, and LiF-Li2MoO4-KCl-KBr and the united stable pentatope LiF-KF-KCl-KBr-K2MoO4 were studied by differential thermal analysis, and phase states in the studied simplexes were determined. The compositions of crystallizing phases in the bulk of the studied tetrahedra and pentatope were confirmed by X-ray powder diffraction analysis.

引用

页码：259 / 267

页数：9

共 27 条

[1] Afanas'eva O. Yu., 2009, IZV VYSSH UCHEBN ZAV, V52, P127
[2] Egortsev G. E., 2008, PHASE EQUILIBRIA CHE
[3] Egunov V. P., 1996, Introduction to Thermal Analysis
[4] Garkushin I. K., 2010, PHASE EQUILIBRIA SYS
[5] Garkushin I. K., 2011, FORMATION CONTINUOUS
[6] Garkushin I.K., 2005, Mashinostroenie-1
[7] LiCl-LiBr-LiVO3 and LiCl-LiBr-Li2MoO4 Ternary Systems
Gubanova, T. V.
Frolov, E. I.
Garkushin, I. K.
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (07) : 1159 - 1162
[8] Iskenderov E. G., 2006, IZV VYSS UCHEB ZAVED, P27
[9] Iskenderov E. G., 2007, P 3 ALL RUSS SCI C P, P13
[10] Kovba L. M., 1991, XRAY POWDER DIFFRACT

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